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WO/1995/015937A1 |
A process for producing difluoromethane and 1,1,1,2-tetrafluoroethane comprising the steps of: (1) reacting methylene chloride and 1,1,2-trichloroethylene with hydrogen fluoride in a first reactor in a gas phase in the presence of a fluo...
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WO/1995/013256A1 |
1,1,1,3,3-Pentafluoropropane is produced in a high yield at a high selectivity by reducing 3-chloro-1,1,1,3,3-pentafluoropropane with hydrogen in a vapor phase in the presence of a noble metal catalyst.
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WO/1995/013336A1 |
Compositions of N(CF3)a(CHF2)b(CH2F)c, where a, b and c are integers from 0 to 3 and a+b+c=3, and CnFmH2n+2-m, where n is an integer from 1 to 3 and m is an integer from 1 to 8, are disclosed. Also disclosed are compositions of N(CF3)3 a...
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WO/1995/013335A1 |
Compositions of 2,2-dichloro-1,1,1-trifluoroethane and 1,1,2,2,3-pentafluoropropane, 1,1,2,3,3-pentafluoropropane or 1,1,1,2,3-pentafluoropropane.
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WO/1995/012566A1 |
A process is disclosed for producing a product comprising CCl2FCF3 substantially free of CClF2CClF2. The process includes (i) contacting a mixture of perhalogenated hydrocarbons which is essentially free of CClF2CClF2 and comprises from ...
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WO/1995/012565A1 |
A process for producing a reaction product comprising C2C13F3 substantially free of 1,2-dichlorotetrafluoroethane is disclosed. The process includes contacting a feed mixture consisting essentially of compounds of the formula C2Cl4-xF2+x...
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WO/1995/012564A1 |
A process for producing CCl2FCF3 substantially free of CC1F2CC1F2 is disclosed. The process includes contacting a feed mixture consisting essentially of C2Cl3F3 where the ratio of CCl2FCClF2 to CCl3CF3 is at least about 1:9 with an isome...
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WO/1995/012563A1 |
A process for producing difluoromethane is disclosed which includes the step of contacting a gaseous mixture containing CH2Cl2 and hydrogen fluoride with a catalyst containing a catalytically effective amount of trivalent chromium suppor...
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WO/1995/010494A1 |
The invention relates to a process for producing pentafluoroethane from unsaturated compounds with two carbon atoms substituted by hydrogen and possibly fluorine, especially trifluoroethylene. The process can also be used in a process fo...
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WO/1995/009140A1 |
The present invention relates to a process for the reduction dechlorination of ClCF2CFClCF2Cl to HCF2CHFCF2H comprising the step of contacting 1,2,3-trichloropentafluoroethane and H2 over a catalyst selected from the group consisting of ...
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WO/1995/008602A1 |
A refrigerant composition for use in a vapour-compression refrigeration apparatus as a replacement for currently used refrigerants R22 and R12 comprises a mixture of pentafluoroethane (R125), tetrafluoroethane (R134a), a hydrocarbon sele...
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WO/1995/008603A1 |
Compositions include mixtures of trifluoromethane and pentafluoropropane; fluoromethane and pentafluoropropane; tetrafluoroethane and heptafluoropropane or pentafluoropropane; 1,1-difluoroethane and heptafluoropropane, or pentafluoroprop...
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WO/1995/006693A1 |
Compositions of 1,1,1,2,3,4,4,5,5,5-decafluoropentane, bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1,1,1,2-tetrafluoro-2-(fluoromethoxy)ethane, 1-(difluoromethoxy)-1,2,2-trifluoroethane, 1-(difluorome...
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WO/1995/006625A1 |
A process for the production of difluoromethane which comprises contacting formaldehyde with hydrogen fluoride in the presence of a catalyst and a chemical dehydrating agent at a temperature below 150 �C. Preferably BF3 is employed as ...
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WO/1995/006021A1 |
A process is disclosed for separating HF from organics by passing a mixture of HF and organics through a column or bed containing a polymer which sorbs the HF leaving an essentially pure organic stream. The HF may be recovered from the p...
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WO/1995/005429A1 |
New ternary compositions of trifluoromethane (R23),1,1,1-trifluoroethane (R143a) and chlorodifluoromethane (R22) suitable as refrigerants for the cryogenic temperature range are disclosed. These compositions qualify in particular as suit...
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WO/1995/005353A1 |
Alternatives to chlorofluorocarbons are provided by the inventive process for synthesizing fluorine-containing products RCFbHc+a-1Hf+d-1FeCR' which may optionally be carried out without the isolation of any intermediate in a single react...
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WO/1995/004020A1 |
A process for the preparation of perfluoroalkyl iodides, especially perfluoroethyl iodide, by reaction of perfluorinated compounds which contain a carbon carbon double bond with ICl in HF solvent in the presence of Lewis acid catalysts. ...
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WO/1995/004021A1 |
The invention relates to a process for preparing hydrofluorocarbons of the formulas CF3(CH2CF2)nF comprising reacting at least one reactant selected from CCl3(CH2CCl2)nCl, CCl3(CH2CF2)nCl or CCl2[(CH2CF2)Cl]2, where n=1 to 3, with hydrog...
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WO/1995/004022A1 |
This invention is related to the preparation of hydrofluorocarbons (HFCs). Specifically, it relates to the manufacture of 1,1,1,3,3-pentafluoropropane, CF3CH2CF2H (HFC-245fa) by the steps comprising (1) the formation of CCl3CH2CCl3 by th...
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WO/1995/003264A1 |
There is provided a process for the preparation of 1,1,1-trichlorotrifluoroethane in which 1,1-dichloro-2,2,2-trifluoroethane is subjected to chlorination by bringing the 1,1-dichloro-2,2,2-trifluoroethane into contact with chlorine with...
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WO/1995/002652A1 |
Azeotrope-like compositions comprising trifluoromethane and carbon dioxide or hexafluoroethane and carbon dioxide are stable and have utility as refrigerants for heating and cooling as well as fire extinguishing compositions.
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WO/1994/029251A1 |
A process for producing 1,1,1,3,3-pentafluoropropane by reducing 1,1,1,3,3,3-pentafluoropropene with hydrogen in the presence of a palladium catalyst in vapor phase at 40 to 300 �C. A process for producing 1,1,1,3,3-pentafluoropropane ...
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WO/1994/029252A1 |
1,1,1,3,3-pentafluoropropane is produced by hydrogenating 2,2,3-trichloro-1,1,1,3,3-pentafluoropropane with at least 4.5 times by equivalent as much hydrogen in the presence of a noble metal catalyst, particularly a palladium catalyst in...
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WO/1994/029249A1 |
A process for converting the isomers of HCFC-123 to HCFC-123 usint TaF5 and/or Nb5 in the absence of HF.
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WO/1994/027940A1 |
A process is disclosed for producing CF3CHFCH2F using vapor phase catalytic dehydrohalogenation to produce CF3CF=CHF and HF, followed by vapor phase catalytic hydrogenation of CF3CF=CHF in the presence of HF.
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WO/1994/027939A1 |
Linear hydrofluorocarbons of the formula XCF2(CF2)nCH2F where X is H or F, and n is 1 to 7 when X is H and 0 to 7 when X is F, are produced by a vapor phase catalytic reaction of HF with corresponding compounds of the formula XCF2(CF2)nC...
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WO/1994/027937A1 |
This invention relates to a liquid phase process for the preparation of RfCHXY by the homogeneous catalytic hydrodechlorination of RfCClXY wherein X and Y are independently H, F, Cl or Rf' provided X and Y are not both Cl, Rf and Rf' are...
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WO/1994/027936A1 |
This invention relates to a liquid phase process for the preparation of RfCHCl2 by the selective homogeneous catalytic hydrodechlorination of RfCCl3 wherein Rf is F, CF3, (CF2)nCl or (CF2)nCF3 by reacting the compound with hydrogen while...
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WO/1994/027938A1 |
This invention relates to a process for producing linear hydrofluorocarbons of the formula: XCF2(CF2)nCH2F, where X is H or F, and n is 1 to 7 when X is H, and n is 0 to 7 when X is F, by a vapor phase catalytic reaction of HF and phosge...
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WO/1994/026837A1 |
Refrigerant compositions include mixtures of hexafluorodimethyl ether and cyclopropane, dimethylether or propylene; bis(difluoromethyl)ether and 2,2,3,4,4-pentafluorooxetane; fluoromethyl trifluoromethyl ether and 2,2,4,4,5,5-hexafluoro-...
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WO/1994/026836A1 |
Azeotrope-like compositions comprising pentafluoroethane and 1,1,1-trifluoroethane are stable and have utility as refrigerants for heating and cooling.
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WO/1994/025418A1 |
A single step, vapor phase process for the chlorofluorination of methane forms trifluoromethane and/or tetrafluoromethane in high yield. A Cr2O3 catalyst is preferred.
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WO/1994/025419A1 |
The present invention discloses azeotropic or azeotrope-like compositions which include HCl that can be employed in a distillation or an extractive distillation process for separating HCl from pentafluoroethane, chloropentafluoroethane, ...
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WO/1994/022973A1 |
This invention relates to compositions of a hexafluoropropane and a hydrofluorocarbon, with the hydrofluorocarbon being hexafluoropropane, pentafluoropropane, tetrafluoropropane, trifluoropropane, difluoropropane, fluoropropane, or (CF3)...
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WO/1994/022794A1 |
A process for the purification of a perfluorochemical composition comprises continuously mixing the perfluorochemical composition, comprising a liquid mixture of inert perfluorochemicals (e.g., perfluoroalkalenes, perfluoroethers, perflu...
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WO/1994/022796A1 |
The invention provides a minimum-boiling-point azeotropic binary mixture substantially composed of hydrogen fluoride (HF) and 1,1-difluoroethane (HFC-152a). Also provided is a process for producing HFC-152a comprising the steps of distil...
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WO/1994/023008A1 |
Azeotropic compositions include a perfluorinated alkane or alkene and an organic solvent, selected from the group consisting of hydrofluorocarbons, hydrochlorofluorocarbons, siloxanes, ethers, 2, 3-dimethyl butane, 2, 3-dimethyl pentane ...
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WO/1994/022797A1 |
The invention provides a minimum-boiling-point azeotropic binary mixture substantially composed of hydrogen fluoride (HF) and pentafluoroethane (HFC-125). Also provided is a process for producing HFC-125 comprising the steps of distillin...
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WO/1994/022793A1 |
Separation of CC1F2CF3 from CHF2CF3 is effectively achieved using either acidic inorganic molecular sieves, non-acidic silicate molecular sieves, or activated carbon.
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WO/1994/021579A1 |
A process for the production of difluoromethane comprising (a) contacting dichloromethane with hydrogen fluoride in the presence of a fluorination catalyst to produce a product stream comprising difluoromethane, monochloromonofluorometha...
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WO/1994/021745A1 |
Azeotrope-like compositions of 1,1,1,2,3,3,3-heptafluoropropane and 1,1-difluoroethane useful as aerosol propellants and blowing agents for plastic foams, heat transfer media, fire suppression agents, gaseous dielectrics or blowing agent...
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WO/1994/021580A1 |
A process for the production of difluoromethane comprising contacting dichloromethane with hydrogen fluoride in the presence of a fluorination catalyst comprising zinc or a compound of zinc and a metal oxide, fluoride or oxyfluoride.
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WO/1994/021714A1 |
A fluororesin molding which is made from a fluororesin composition comprising 0.1 to 30 % by weight of a carbonaceous material and is fluorinated on the surface. The molding is produced by molding a fluororesin composition comprising 0.1...
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WO/1994/020588A1 |
A new set of effective, environmentally safe, nonflammable, low-toxicity refrigerants, solvents, foam blowing agents, propellants, and firefighting agents is disclosed. The agents are clean, electrically nonconductive, and have short atm...
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WO/1994/020587A1 |
Compositions include compositions of hexafluoropropane and butane, cyclopropane, isobutane, propane or dimethyl ether, including mixtures of 1,1,2,2,3,3-hexafluoropropane and butane, cyclopropane, isobutane or propane; 1,1,1,2,2,3-hexafl...
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WO/1994/020441A1 |
A process for producing HFC-125 by dividing the reaction system into a first reaction zone for the vapor-phase reaction of mainly perchloroethylene with HF in the presence of a catalyst and a second reaction zone for the vapor-phase reac...
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WO/1994/019301A1 |
The invention generally relates to a process for the purification of a component of a binary azeotrope in which the composition of the azeotrope changes by about 10 mole percent with pressure comprising: a) subjecting a binary azeotrope ...
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WO/1994/018282A1 |
This invention relates to compositions that include at least one hydrocarbon and at least one fluorinated species. Such compositions may be used as refrigerants, cleaning agents, expansion agents for foams such as polyolefins and polyure...
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WO/1994/017020A1 |
A process for producing 1,1,1,4,4,4-hexafluoro-2-butenes comprising a mixture of 1,1,1,4,4,4-hexafluoro-2,3-dichloro-2-butene, 1,1,1,4,4,4-hexafluoro-2-chloro-2-butene and 1,1,1,4,4,4-hexafluoro-2-butene by the reaction of at least one m...
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