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JP61143353 |
PURPOSE: The reaction between a phenol and a thiocyanate salt gives a compound which is used as a feedstock of medicines such as an antiulcerative through a shortened process by without use of a mercury compound which has possibility of ...
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JP61007251 |
PURPOSE: To obtain the titled compound easily at a low cost, by reacting an aromatic compound having at least one substituent group selected from amino group and hydroxyl group with a thiocyanate and a halide of a sulfur-containing oxy a...
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JP60260556 |
NEW MATERIAL:A compound expressed by formula I (X is halogen; Y is alkyl). EXAMPLE: 1-Ethoxy-2-bromoethyl isothiocyanate. USE: Useful as a synthetic intermediate for thiazole derivatives having anti-inflammatory action, and capable of pr...
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JP60222458 |
NEW MATERIAL:A compound of formula I (R is 1W10C alkyl; ring A is 1,4- trans-cyclohexylene or 1,4-phenylene). EXAMPLE: p-[4-trans-(4'-trans-Propylcyclohexyl)cyclohexyl]phenyl isothiocyanate. USE: Liquid crystal display elements: it keeps...
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JP60146868 |
NEW MATERIAL:The 4-(trans-4'-alkylcyclohexyl)phenyl isothiocyanate of formula (R is 1W10C alkyl). USE: Useful as a liquid crystal material. It is a nematic liquid crystal substance having low viscosity and positive dielectric anisotropy,...
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JP60136555 |
NEW MATERIAL:A compound expressed by the formula (R is 1W10C alkyl). EXAMPLE: 4-Isothiocyanatophenyl trans-4-propylcyclohexanecarboxylate. USE: A nematic liquid crystal substance having positive dielectric anisotropy, useful as a compone...
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JP60126262 |
NEW MATERIAL:A compound of formula I (X is O, S; A is halogen, lower alkyl, lower alkoxy; R is F-substituted lower alkyl; m is 0W4). EXAMPLE: 3-Chloro-4-(2,2,2-trifluoroethylthio)phenyl isocyanate. USE: Synthetic intermediate of benzoylu...
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JP60072858 |
PURPOSE: The reaction between methylene bromide or iodide and an alkali metal thiocyanate is carried out in a solvent of a specific polyhydric alcohol to produce the titled compound used as fungicide through simple process in high qualit...
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JP60006654 |
NEW MATERIAL:The compound of formula I (R1 is phenyl or phenoxy; R2 and R3 are lower alkyl or lower alkoxy; R4 is H, lower alkyl or lower alkoxy). EXAMPLE: N-(2-Biphenylylsulfonyl) N'-(4,6-dimethoxy-1,3,5-triazin-2-yl) N"-(methoxy)guanid...
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JP60001157 |
NEW MATERIAL:The compound of formula I [X is nitro, 2-nitrovinyl, amino, the group of formula II (A' is O or S; R2 is lower alkyl, etc.), etc.; Y is lower alkyl, lower alkenyl, nitro, etc.; z is H, OH, lower alkyl, etc.; R is H or -OR1 (...
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JP59231005 |
PURPOSE: The titled composition showing improved fungicidal action on a wide range of kinds of molds, containing one or more of an aniline derivative, a benzimidazole fungicide, a thiophanate fungicide or a cyclic imide fungicide as acti...
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JP59210059 |
NEW MATERIAL:The compound of formula I [X is nitro, amino, thioisocyanato, group of formula II (A' or O or S; R3 is lower alkyl, lower alkenyl, etc.), etc.; Y is lower alkyl, lower alkoxy, H, etc.; R1 is lower alkyl, lower alkenyl, etc.;...
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JP59210064 |
NEW MATERIAL:The compound of formula I [X is nitro, amino, thioisocyanato, group of formula II (A' is O or S; R2 is lower alkyl, lower alkenyl, etc.), etc.; Y is lower alkyl, lower alkoxy, H, etc.; A is O or S; B is lower alkyl, lower al...
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JP59210004 |
PURPOSE: An agricultural and horticultural fungicidal composition having high effect even with a low concentration, capable of preventing fungi resistant to chemicals from spreading, obtained by combining an aniline derivative with any o...
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JP59210053 |
NEW MATERIAL:The compound of formula I [X is nitro, amino, thioisocyanato, etc.; Y is lower alkyl, lower alkenyl, H, halogen, etc.; R is H or -OR1 (R1 is lower alkyl, lower alkenyl, etc.); A is O or S; B is lower alkyl, lower alkenyl, ph...
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JP59200230 |
PURPOSE: To obtain a uniform image high in the max. density irrespective of variation of developing temp. by using a specified mercapto compd. as a nucleating agent (fogging agent) to be added to a photosensitive silver halide photograph...
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JP59170840 |
PURPOSE: To provide a titled material which has improved sensitivity, has a good granular characteristic, permits quick processing to hard contrast and has a long shelf life by incorporating a specific compd. in a layer to be provided on...
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JP59059661 |
PURPOSE: To prepare the titled compound economically in an industrial scale in high yield, by reacting bromochloromethane with a thiocyanic acid salt in the presence of water using polyethylene glycol and/or its alkyl ether, etc. as a ca...
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JP58183661 |
NEW MATERIAL:A compound of formula I (X and Y are halogen; R is H or methyl; Z is cyano or thiocyano, etc.). EXAMPLE: 2,2-Dichloro-3,3-dimethylcyclopropylmethyl thiocyanate. USE: Useful as an intermediate for preparing agricultural chemi...
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JP58152842 |
NEW MATERIAL:The (2,2-dihaloethenyl) cyclopropanecarboxylic acid ester derivative of formulaI [R is benzyl, α-cyanobenzyl, or α-cyano-2-pyridylmethyl; R1 is hydroxymethyl, halomethyl, cyanomethyl, azidomethyl, thiocyanatomethyl, (subst...
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JP58090546 |
PURPOSE: The thioalkylation of a halogenated alkyl is followed by amination of the product and conversion of the resultant NH2 group into NCS to give the titled compound used as a flavor through a simplified process. CONSTITUTION: A diha...
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JP58083669 |
NEW MATERIAL:A compound shown by the formulaI(X is O or S; R is lower alkyl; Y is halogen, lower alkyl, lower alkoxy, lower thioalkoxy, trifluoromethyl, nitro, dialkylamino, thiocyanato, alkoxycarbonyl or alkoxycarbonylmethoxy which may ...
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JP58057324 |
PURPOSE: A nucleophilic reagent and a perfluoroalylaryliodonium compound are used to effect the perfluoroalkylation of a compound such as ethylene, as well as make the product nucleophilic, thus producing the titled compound used as an i...
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JP58049362 |
PURPOSE: Water is used as a solvent to obtain an alkali metal salt of dithiocarbamic acid under specific conditions and the product is made to react with an inorganic alkali, thus permitting the reaction in an aqueous medium and producin...
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JP57175158 |
NEW MATERIAL:A compound shown by the formulaI(X1 is halogen; X2 is halogen, HiY is H, halogen, alkyl, aryl, haloalkyl, alkoxy, haloalkoxyl, nitro, cyano, etc.; n is 1W5). EXAMPLE: N-[4-(3-Chlorophenylazo)phenyl]-N'-(2,6-difluorobenzoyl)u...
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JP57134461 |
PURPOSE: To prepare the titled mixture which can be converted easily to t-alkyl isothiocyanate useful as an intermediate for pharmaceuticals and pesticides, with one-step reaction, by using an easily available, inexpensive tert-alcohol a...
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JP57004967 |
PURPOSE: To obtain the titled compound useful as a raw material for 1-mercapto- 3-naphthol industrially and advantageously, by reacting a 1-halogeno-2-naphthol with a thiocyanate in an organic solvent under heating. CONSTITUTION: A 1-hal...
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JP57004944 |
NEW MATERIAL:The compound of formula I [R1 is nitro, isothiocyanato, -OR3 (R3 is lower haloalkyl, etc.), etc.; A is H, CN or ethynyl; R2 is group of formula II [R6 is H or CH3; when R6 is H, R7 is cyclopentylidenemethyl, XC=C- (X is halo...
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JP56158758 |
PURPOSE: To obtain the titled compound useful as a synthetic raw material for a tetrazole which is a raw material for cephalosporin antibiotic industrially and advantageously, by reacting a dithiocarbamate with cyanamide. CONSTITUTION: (...
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JP56158757 |
PURPOSE: To obtan 2-dimethylamino-1,3-dithiocyanatopropane useful as an insecticide and an acaricide industrially and advantageously, by reacting a dimethylamino-bis(arenesulfonylthio)propane with a prussiate. CONSTITUTION: A 2-dimethyla...
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JP56059747 |
NEW MATERIAL:A substituted cyclopropanecarboxylic acid ester of formula I (A is H, cyano or ethynyl). EXAMPLE: 3-Phenoxybenzyl 2,2-dimethyl-3-thiocyanatomethylcyclopropanecarboxylate. USE: Insecticide having higher insecticidal activity ...
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JP56039018 |
PURPOSE: To provide a remedy for cancer, having low toxicity, effective at a low dose, and containing a specific isothiocyanate compound as a main effective component. CONSTITUTION: A composition containing 2,3,4,5,6-penta-ortho-acetyl-D...
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JP56010164 |
NEW MATERIAL:Isovaleric ester derivatives of formula I (R is thiocyanate, isothiocyanate; n is 1 or 2) and their optically active isomers. EXAMPLE: m'-Thiocyanatomethoxy-α'-cyanobenzyl-α- ( p-chlorophenyl ) -isovalerate of formula I wh...
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JP55129259 |
NEW MATERIAL:An isovaleric acid ester derivative I (R is cyano or thiocyanate) and its optical isomer. EXAMPLE: p'-Cyanomethyl-α-cyanobenzyl α-(p-chlorophenyl)isovalerate. USE: Insecticides and miticides. Remarkably useful for control ...
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JP55049347 |
PURPOSE: To obtain an iso(thio)cyanate industrially advantageously, by converting an N-substituted (thio)carbamate into a lithio or magnesio compound, which is reacted with carbon disulfide or sulfur dioxide under mild conditions. CONSTI...
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JP55031012 |
NEW MATERIAL:The title compound of formula I (R1 is H, lower alkylcarbonyl, lower alkoxycarbonyl, etc.; R2 is phenyl which may be substituted by lower alkyl, lower alkoxy, lower alkylthio, etc., or naphthyl). EXAMPLE: N-(1'-p-methylpheno...
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JP54109969 |
PURPOSE: Thiazole derivatives having a substituent in the 2-position useful for preparation of an anti-inflammatory agent and others are derived from a novel compound of 1-alkoxy-2-halogenoethylisothiocyanate in high yield. CONSTITUTION:...
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JP54055550 |
NEW MATERIAL:Compounds of formula I (R1 is alkoxy, hydroxy, amino, alkylamino, diakylamino, arylamino, tetrahydrofurfurylamino, or morpholino; R2 is alkyl alkoxycarbonyl; R3 is alkyl alkoxy, dialkylamino, halogen) and their salts. EXAMPL...
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JP53119822 |
PURPOSE: To obtain the title compound useful as an intermediate for the synthesis of pesticides, pharmaceuticals, or inductrial bactericides, in high yield, by the reaction of 2-dimethylaminoethyldithiocarbamic acid and a sodium hypochlo...
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JP53112815 |
PURPOSE: To obtain the title compound, useful as an intermediate of e.g. pesticides, pharmaceuticals or industrial germicides, easily and in high yield without using poisonous substances, by removal of hydrogen sulfide from dithiocarbami...
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JP52018818 |
PURPOSE: Dithiocyanate drugs of low toxicity which prevent hydrozoas from depositing on waterways, underwater constructions, fish nets, etc.
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JP51130528 |
PURPOSE: A controlling agent or coating, specifically controlling against harmful organisms in water (purple shells, acorn shells, sea mosses, sea lettuces, etc.) especially highly active against their larvae with low concentration, with...
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