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Title:
高立体規則性ポリブチレンポリマー及びその高活性な調製方法
Document Type and Number:
Japanese Patent JP2007504293
Kind Code:
A
Abstract:
Disclosed is a process for the preparation of a high stereospecific (isotactic) polybutylene polymer comprising the step of polymerizing a reactive monomer, 1-butene, which is used or is not used as a solvent, in the presence of catalyst and inert gas. According to the present invention, it is possible to prepare a high stereospecific polybutylene polymer in much higher activity than that of any other known processes for the preparation of a high stereospecific polybutylene polymer. The high stereospecific polybutylene polymer according to the present invention is a homopolymer of 1-butene, or a copolymer containing a-olefin and up to 40% by weight of a comonomer, wherein titanium in the catalyst residues is not detected in the ppm level, stereospecificity (Isotactic Index, mmmm %) determined by 13C-NMR is 96 or more, molecular weight distribution (Mw/Mn) is 3-6, and molecular weight distribution (Mw/Mn) can be controlled to 8 or more.

Inventors:
Hong Sung Pyo
Park Min Kyu
Kim Dok Kyung
Hoang Suk Jun
Application Number:
JP2006524559A
Publication Date:
March 01, 2007
Filing Date:
March 31, 2004
Export Citation:
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Assignee:
IREM Technology Holdings Inc.
International Classes:
C08F10/08; C08F2/00; C08F10/00; C08F110/08
Domestic Patent References:
JPS6424812A1989-01-26
JPS63230716A1988-09-27
JP2005509062A2005-04-07
JPS6351409A1988-03-04
JPH03126704A1991-05-29
Attorney, Agent or Firm:
Masatsugu Suzuki
Kenichi Wakui
Norihiro Yamamoto
Kazunaga Suzuki