Title:
アルコールおよびアンモニアからアミンを調製する方法
Document Type and Number:
Japanese Patent JP2011530408
Kind Code:
A
Abstract:
The present invention provides novel ruthenium based catalysts, and a process for preparing amines, by reacting a primary alcohol and ammonia in the presence of such catalysts, to generate the amine and water. According to the process of the invention, primary alcohols react directly with ammonia to produce primary amines and water in high yields and high turnover numbers. This reaction is catalyzed by novel ruthenium complexes, which are preferably composed of quinolinyl or acridinyl based pincer ligands.
Inventors:
David Millstain
Chidambaram Gunanasan
Chidambaram Gunanasan
Application Number:
JP2011522611A
Publication Date:
December 22, 2011
Filing Date:
August 10, 2009
Export Citation:
Assignee:
YEDA RESEARCH AND DEVELOPMENT COMOPANY LIMITED
International Classes:
B01J31/24; C07C209/14; C07C211/03; C07C211/17; C07C211/27; C07C211/29; C07C213/02; C07C217/08; C07C217/58; C07F9/64; C07F19/00; C07B61/00; C07F5/02; C07F15/00
Domestic Patent References:
| JP2001506644A | 2001-05-22 | |||
| JPS55111446A | 1980-08-28 |
Foreign References:
| US20090112005A1 | 2009-04-30 |
Other References:
JPN6015012589; Ｇｕｎａｎａｔｈａｎ，Ｃ． ｅｔ ａｌ．: 'Ｄｉｒｅｃｔ Ｃｏｎｖｅｒｓｉｏｎ ｏｆ Ａｌｃｏｈｏｌｓ ｔｏ Ａｃｅｔａｌｓ ａｎｄ Ｈ２ Ｃａｔａｌｙｚｅｄ ｂｙ ａｎ Ａｃｒｉｄｉｎｅ-Ｂａｓｅｄ Ｒｕｔｈｅｎｉｕｍ Ｐｉｎｃｅｒ Ｃｏｍｐ' Ｊ．ＡＭ．ＣＨＥＭ．ＳＯＣ． Ｖｏｌ．１３１，Ｎｏ．９, 2009, ｐａｇｅ．３１４６，３１４７
JPN6015012591; Ｇｕｎａｎａｔｈａｎ，Ｃ． ｅｔ ａｌ．: 'Ｓｅｌｅｃｔｉｖｅ Ｓｙｎｔｈｅｓｉｓ ｏｆ Ｐｒｉｍａｒｙ Ａｍｉｎｅｓ Ｄｉｒｅｃｔｌｙ ｆｒｏｍ Ａｌｃｏｈｏｌｓ ａｎｄ Ａｍｍｏｎｉａ' Ａｎｇｅｗ． Ｃｈｅｍ． Ｖｏｌ．１２０, 200810, ｐａｇｅ．８７８９-８７９２
JPN6015012591; Ｇｕｎａｎａｔｈａｎ，Ｃ． ｅｔ ａｌ．: 'Ｓｅｌｅｃｔｉｖｅ Ｓｙｎｔｈｅｓｉｓ ｏｆ Ｐｒｉｍａｒｙ Ａｍｉｎｅｓ Ｄｉｒｅｃｔｌｙ ｆｒｏｍ Ａｌｃｏｈｏｌｓ ａｎｄ Ａｍｍｏｎｉａ' Ａｎｇｅｗ． Ｃｈｅｍ． Ｖｏｌ．１２０, 200810, ｐａｇｅ．８７８９-８７９２
Attorney, Agent or Firm:
Kenji Sugimura
Kazuyuki Tomita
Suzuki Kazutoshi
Kazuyuki Tomita
Suzuki Kazutoshi