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Title:
ジアンヒドロヘキシトールのジアルキルカーボネートを調製するための方法
Document Type and Number:
Japanese Patent JP2013506645
Kind Code:
A
Abstract:
A method for preparing dialkyl carbonates of dianhydrohexitol, includes the following steps: (a) preparing an initial reaction mixture containing at least one dianhydrohexitol, at least two mole equivalents of a dialkyl carbonate of formula and a transesterification catalyst; (b) heating the reaction mixture to a temperature greater than or equal to the boiling temperature of the formed alcohol, or of the azeotrope thereof, in a reaction chamber preferably provided with a rectification column including a sufficient number of theoretical distillation plates to separate the resulting alcohol from the reaction mixture. Certain dialkyl carbonates of dianhydrohexitols produced by the method and the use thereof for synthesizing synthetic polymers are also described.

Inventors:
Patrick Fuel
Machias Ibert
Emily Jocian
Pietro Tund
Fabio Arico
Application Number:
JP2012531482A
Publication Date:
February 28, 2013
Filing Date:
September 30, 2010
Export Citation:
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Assignee:
Rocket fleure
International Classes:
C07D493/04; C07B61/00
Domestic Patent References:
JPH06261774A1994-09-20
JP2008024919A2008-02-07
JP2003292603A2003-10-15
JP2004247274A2004-09-02
Foreign References:
WO2008069725A12008-06-12
Other References:
JPN6014050368; J. Appl. Polym. Sci. 86, 2002, 872-880
JPN6014050371; Macromolecules 39, 2006, 9064-9070
Attorney, Agent or Firm:
Yasuhiko Murayama
Masatake Shiga
Takashi Watanabe
Shinya Mitsuhiro