Title:
ポリビフェニールスルホンエーテル及びポリエーテルスルホンの共重合体の調製方法
Document Type and Number:
Japanese Patent JP2013508516
Kind Code:
A
Abstract:
A method for preparing terpolymer of poly (biphenyl sulfone ether) and poly (ether sulfone) comprises: adding high-temperature organic solvent into a flask, stirring and heating to 80°C, adding 4,4'-dichlorodiphenylsulfone,4,4'-Bis(4-chlorophenyl)sulionyl-1,1'-biphenyl and 4,4'-dihydroxydiphenylsulfone with solid content of 20-35%; stirring until monomers are completely dissolved, heating to 100°C, adding salt-forming agent and xylene; stirring while heating so that salt-forming reaction begins in the system, wherein the system temperature is controlled between 190°C and 210°C; when the amount of water discharged reaches the theoretical value, the first stage of salt-forming reaction is finished; heating the system to 230-236°C, and maintaining for 3-4 hours to obtain polymer viscous liquid; and refining the polymer viscous liquid to obtain a terpolymer containing different structural units in the molecular chain, wherein the Tg of the terpolymer, can be regulated by changing the ratio of the two dichloro-containing monomers.
Inventors:
Ochon Wen
Marontan
Marontan
Application Number:
JP2012535587A
Publication Date:
March 07, 2013
Filing Date:
October 26, 2010
Export Citation:
Assignee:
Kinfa SCI & Tech Company Limited
International Classes:
C08G65/40; C08G75/23
Domestic Patent References:
| JPS63152633A | 1988-06-25 | |||
| JPS6422964A | 1989-01-25 |
Foreign References:
| WO2007039538A1 | 2007-04-12 |
Attorney, Agent or Firm:
Maeda patent office
Hiroshi Maeda
Hiroshi Takeuchi
Takahisa Shimada
Yuji Takeuchi
Katsumi Imae
Kazunari Ninomiya
Tomoo Harada
Seki Kei
Yasuya Sugiura
Daisuke Kawabe
Masanori Hasegawa
Tsuguya Iwashita
Koji Fukumoto
Ryo Maeda
Mawaki Hachizo
Yukichi Matsunaga
Kenji Kawakita
Shohei Okazawa
Hiroshi Maeda
Hiroshi Takeuchi
Takahisa Shimada
Yuji Takeuchi
Katsumi Imae
Kazunari Ninomiya
Tomoo Harada
Seki Kei
Yasuya Sugiura
Daisuke Kawabe
Masanori Hasegawa
Tsuguya Iwashita
Koji Fukumoto
Ryo Maeda
Mawaki Hachizo
Yukichi Matsunaga
Kenji Kawakita
Shohei Okazawa