二酸化炭素と水素との反応によってギ酸を製造するための方法

Japanese Patent JP2014508119

A

The invention relates to a method for producing formic acid by reacting carbon dioxide (1) with hydrogen (2) in a hydrating reactor (I) in the presence of a catalyst comprising an element from the 8th, 9th, or 10th group of the periodic system; a tertiary amine containing at least twelve carbon atoms per molecule; and a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols, and butanols, forming formic acid / amine adducts as intermediate products, which are subsequently thermally split, wherein a tertiary amine having a boiling point at least 5°C higher than formic acid is used, and wherein a reaction mixture comprising the polar solvent, the formic acid / amine adducts, the tertiary amine, and the catalyst forms from the reaction in the hydrating reactor (I) and is discharged as a discharge (3) from the reactor.

JPS5540664	RECOVERY OF ACRYLIC ACID BY RECYCLING QUENCHING
WO/2000/046174	A METHOD OF PREPARING CYCLOHEXANECARABOXYLIC ACID USING [2+4] DIELS-ALDER REACTION

Thomas shoop
Donata Maria Fleece
Rocco Pasier
Claus-Deter Mall
Martin shafer
Stephan Rittinger
Petra Decart
Peter Basler

JP2013545210A

April 03, 2014

December 15, 2011

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BASF SE

C07C51/00; C07C51/44; C07C51/48; C07C53/02; C07B61/00

JPH0291038A	1990-03-30
JPS62500303A	1987-02-05
JPS60209260A	1985-10-21
JPH0291038A	1990-03-30
JPS62500303A	1987-02-05
JPS60209260A	1985-10-21

WO2012000799A1	2012-01-05
WO2012000823A1	2012-01-05
WO2012000964A1	2012-01-05
WO2010149507A2	2010-12-29
WO2008116799A1	2008-10-02
WO2006021411A1	2006-03-02
WO2012000799A1	2012-01-05
WO2012000823A1	2012-01-05
WO2012000964A1	2012-01-05
WO2010149507A2	2010-12-29
WO2008116799A1	2008-10-02
WO2006021411A1	2006-03-02

Einzel Felix-Reinhard
Takuya Kuno

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