Title:
高級炭化水素選択的合成用の鉄またはコバルト含有フィッシャー・トロプシュ触媒
Document Type and Number:
Japanese Patent JP2014516765
Kind Code:
A
Abstract:
Cryptomelane-type manganese oxide octahedral molecular sieves (OMS-2) supported Fe and Co catalysts are utilized in a method for producing hydrocarbons by a Fischer-Tropsch mechanism. The hydrocarbon producing method includes providing a catalyst of a manganese oxide-based octahedral molecular sieve nanofibers with an active catalyst component of at least one of iron, cobalt, nickel, copper, manganese, vanadium, zinc, and mixtures thereof, and further containing an alkali metal. The formation of iron carbides and cobalt carbides by exposing the catalyst to conditions sufficient to form those carbides is also taught. After the catalyst has been appropriately treated, a carbon source and a hydrogen source are provided and contacted with the catalyst to thereby form a hydrocarbon containing product. The catalyst have high catalytic activity and selectivity (75%) for C2+ hydrocarbons in both CO hydrogenation and CO2 hydrogenation. Highly selective syntheses of high value jet fuel, C2-C6 alkenes, C2-C6 carboxylic acids; α-hydroxylic acids and their derivatives have been realized by tuning the oxidation ability of OMS-2 supports and by doping with Cu2+ ions.
Inventors:
Swives, Stephen, Elle.
Bo Shun, Who
Cradler, Eric, Roland
Brooks, Christopher, James
Bo Shun, Who
Cradler, Eric, Roland
Brooks, Christopher, James
Application Number:
JP2014502653A
Publication Date:
July 17, 2014
Filing Date:
March 26, 2012
Export Citation:
Assignee:
Honda motor industry stock company
UNIVERSITY OF CONNECTICUT
UNIVERSITY OF CONNECTICUT
International Classes:
B01J29/03; B01J23/889; C07C1/04; C07C1/12; C07C9/00; C07C11/00; C07C15/00; C07C45/00; C07C45/49; C07C47/00; C07C51/10; C07C53/08; C07C53/122; C07C59/01; C07D309/30; C07B61/00
Domestic Patent References:
| JP2007527783A | 2007-10-04 | |||
| JP2010070548A | 2010-04-02 | |||
| JP2010070548A | 2010-04-02 | |||
| JP2007527783A | 2007-10-04 |
Foreign References:
| US8987160B2 | 2015-03-24 | |||
| WO1995025693A1 | 1995-09-28 | |||
| WO1995025693A1 | 1995-09-28 | |||
| US8987160B2 | 2015-03-24 |
Attorney, Agent or Firm:
Isono Dozo