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Title:
ホスフィン配位パラジウムスルホナートパラダサイクル
Document Type and Number:
Japanese Patent JP2015527300
Kind Code:
A
Abstract:
パラジウム前触媒ならびにそれらを製造および使用する方法を記載する。パラジウム前触媒は、これまでに記載されたパラジウム前触媒に比べて安定性および反応性が改善された。

Inventors:
ブルーノ,ニコラス シー
バックウォルド,スティーヴン エル
Application Number:
JP2015516006A
Publication Date:
September 17, 2015
Filing Date:
March 13, 2013
Export Citation:
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Assignee:
マサチューセッツ インスティテュート オブ テクノロジー
International Classes:
C07F15/00; B01J31/24; C07B39/00; C07B41/04; C07B43/04; C07B43/06; C07C17/093; C07C17/32; C07C22/08; C07C25/13; C07C25/18; C07C41/30; C07C43/225; C07C45/63; C07C49/807; C07C213/02; C07C217/84; C07C217/92; C07C227/08; C07C229/60; C07C231/08; C07C233/75; C07C253/30; C07C255/50; C07C255/54; C07C255/58; C07C319/20; C07C323/20; C07F7/10
Domestic Patent References:
JP2011508726A2011-03-17
Foreign References:
Other References:
KARAMI, KAZEM; RAHIMI, NASER; SHEHNI, MAHLAGHA BAHRAMI: "Cyclopalladated complexes of 2-phenylaniline and their catalytic activity in Suzuki and Heck rea", TETRAHEDRON LETTERS, vol. 53(19), JPN6016048679, 2012, pages 2428-2431
KARAMI, KAZEM; RIZZOLI, CORRADO; RAHIMI, NASER: "Synthesis and characterization of 2-phenylaniline cyclopalladated complexes", TRANSITION METAL CHEMISTRY (DORDRECHT, NETHERLANDS), vol. 36(8), JPN6016048680, 2011, pages 841-846
ALBERT, JOAN; GRANELL, JAUME; ZAFRILLA, JAVIER; FONT-BARDIA, MERCE; SOLANS, XAVIER: "The cyclopalladation reaction of 2-phenylaniline revisited", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 690(2), JPN6016048681, 2005, pages 422-429
KINZEL TOM: "A NEW PALLADIUM PRECATALYST ALLOWS FOR THE FAST SUZUKI-MIYAURA COUPLING REACTIONS 以下備考", J.AM.CHEM.SOC., vol. V132 N40, JPN5015007470, 13 October 2010 (2010-10-13), pages 4073 - 14075
BISCOE, MARK R.; FORS, BRETT P.; BUCHWALD, STEPHEN L.: "A New Class of Easily Activated Palladium Precatalysts for Facile C-N Cross-Coupling Reactions a", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 130(21), JPN6016048690, 2008, pages 6686-6687
BEDFORD, ROBIN B.; CAZIN, CATHERINE S. J.; COLES, SIMON J.; GELBRICH, THOMAS; HORTON, PETER N.;: "High-Activity Catalysts for Suzuki Coupling and Amination Reactions with Deactivated Aryl Chlori", ORGANOMETALLICS, vol. 22(5), JPN6016048691, 2003, pages 987-999
KARAMI, KAZEM; RAHIMI, NASER; SHEHNI, MAHLAGHA BAHRAMI: "Cyclopalladated complexes of 2-phenylaniline and their catalytic activity in Suzuki and Heck rea", TETRAHEDRON LETTERS, vol. 53(19), JPN6016048679, 2012, pages 2428-2431
KARAMI, KAZEM; RIZZOLI, CORRADO; RAHIMI, NASER: "Synthesis and characterization of 2-phenylaniline cyclopalladated complexes", TRANSITION METAL CHEMISTRY (DORDRECHT, NETHERLANDS), vol. 36(8), JPN6016048680, 2011, pages 841-846
DAMIEN PRIM 他: "Palladium-catalysed reaction of aryl halides with soft, non-organometallic nucleophiles", TETRAHEDRON, vol. 58, JPN6016048683, 2002, pages 2041-2075
WATSON, DONALD A.; SU, MINGJUAN; TEVEROVSKIY, GEORGIY; ZHANG, YONG; GARCIA-FORTANET, JORGE; KINZ: "Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides", SCIENCE (WASHINGTON, DC, UNITED STATES), vol. 325(5948), JPN6016048684, 2009, pages 1661-1664
CHO, EUN JIN; SENECAL, TODD D.; KINZEL, TOM; ZHANG, YONG; WATSON, DONALD A.; BUCHWALD, STEPHEN L: "The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides", SCIENCE (WASHINGTON, DC, UNITED STATES), vol. 328(5986), JPN6016048685, 2010, pages 1679-1681
Attorney, Agent or Firm:
柳田 征史
佐久間 剛