Title:
開放型金属カルボニルクラスターの合成
Document Type and Number:
Japanese Patent JP2015533814
Kind Code:
A
Abstract:
本発明は、結合した配位子の選択的酸化による、新規の安定な開放型金属クラスターの合成を対象とする。この合成は、例えば、特定のカルボニル配位子の脱カルボニル化のための、アミンをベースとするオキシダントの使用を含む。この合成はまた、酸による、結合したアミン基のさらなる除去も含むことができる。得られた金属クラスターは、カルボニルの空位を含む、配位的に不飽和な部位を含有する。得られた金属クラスターは、種々の化学転換において触媒として使用することができる。
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Inventors:
Katz, Alexander
Cooperman, Alexander
Ocrat, alexander
Rannebaum, Ron, Cee.
Ouyang, Xiao Inn
Cooperman, Alexander
Ocrat, alexander
Rannebaum, Ron, Cee.
Ouyang, Xiao Inn
Application Number:
JP2015533285A
Publication Date:
November 26, 2015
Filing Date:
September 24, 2013
Export Citation:
Assignee:
Chevron U.S.A. Inc.
The Regents of The University of California
The Regents of The University of California
International Classes:
C07F9/50; B01J31/24; C07C5/03; C07C9/06; C07C211/04
Domestic Patent References:
| JPH09301986A | 1997-11-25 | |||
| JPH01228555A | 1989-09-12 | |||
| JP2008036601A | 2008-02-21 | |||
| JP2015533647A | 2015-11-26 |
Foreign References:
| WO2011050300A1 | 2011-04-28 |
Other References:
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"Opening of metal carbonyl cluster complexes by ligand addition. Synthesis and structural characteriz", J. AM. CHEM. SOC, vol. 1992, 114 (5), pp 1909-1910, JPN6017009617, 1992, ISSN: 0003688157
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ORGANOMETALLICS, vol. 29, JPN6017009625, 2010, pages 61 - 75, ISSN: 0003688160
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ROIYAL SOCIETY OF CHEMISTRY, DALTON TRANSACTIONS, JPN6017009628, 1990, pages 1221 - 1229, ISSN: 0003688162
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