水溶性または水膨潤性のスルホ基含有コポリマー、その製造方法およびその使用

Title:

水溶性または水膨潤性のスルホ基含有コポリマー、その製造方法およびその使用

Document Type and Number:

Japanese Patent JP4187859

Kind Code:

B2

Abstract:

Water-soluble or -expandable, sulfo group-containing copolymers with monomer units derived from (meth)acrylamido-alkanesulfonic acid, optionally substituted (meth)acrylamide and/or N-vinylamide, (meth)acryloyloxy-alkyl- or (meth)acrylamidoalkyl-trialkyl-ammonium halide and other (meth)acrylate ester or vinyl monomers. Water-soluble or -expandable, sulfo group-containing copolymers comprise (a) 3-96 mol% units of formula (I), (b) 3-96 mol% units (IIa) and/or (IIb), (c) 0.05-75 mol% units (III) and (d) 0.01-50 mol% units (IV); R<1> = H or methyl; R<2>-R<4> = H, 1-6C aliphatic hydrocarbyl or 6-14C aryl (optionally substituted with 1-6C alkyl groups); M = H, mono- or divalent metal cation, ammonium and/or organic amine residue; a = 0.5 or 1; R<5>, R<6> = H, optionally substituted 1-20C aliphatic hydrocarbyl, 5-8C cycloaliphatic hydrocarbyl or 6-14C aryl, or (if Q is not H in IIb) R<5> + R<6> may be -CH2-(CH2)y-; y = 1-4; Q = H or -CHR<5>R<7>; R<7> = H, 1-4C aliphatic hydrocarbyl, -COOH or -COOMa; Y = O, NH or NR<5>; R<8> = R<5> or R<6>; X = anion, especially halide, 1-4C alkylsulfate or 1-4C alkylsulfonate; x = 1-6; Z = -COO(CmH2mO)n-R<5> or -(CH2)p-O(CmH2mO)n-R<5>; m = 2-4; n = 0-200; p = 0-20. An Independent claim is also included for a process for the production of these copolymers from the corresponding monomers by aqueous solvent- or gel-polymerisation or inverse suspension polymerisation in organic solvent at -20 to 250 degrees C.

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Inventors:

Gerhard Albrecht
Christian hoover
Manfred Schubeck
Joseph Weichmann
Alfred Cologne

Application Number:

JP3728099A

Publication Date:

November 26, 2008

Filing Date:

February 16, 1999

Export Citation:

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Assignee:

Construction Research & Technology GmbH

International Classes:

C04B24/26; C04B24/16; C04B24/32; C08F2/10; C08F2/32; C08F210/14; C08F216/14; C08F220/34; C08F220/54; C08F220/58; C08F220/60; C08F226/02; C08F246/00; C09D133/24

Domestic Patent References:

JP9225499A
JP3265690A

Attorney, Agent or Firm:

Toshio Yano
Toshiomi Yamazaki
Takuya Kuno
Hiroshi Sugimoto
Einzel Felix-Reinhard

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