To solve a problem that a conventional MONOS has a configuration for storing charges in SiN, but the charge storage amount is not sufficient, the variational width of a threshold voltage cannot be made large, and consequently high electric charge density by means of dopant introduction cannot be realized by a technique of introducing lanthanoids into HfO
A nonvolatile semiconductor memory includes an electric charge accumulating layer, having a configuration in which a metal oxide having sufficiently higher dielectric constant than silicon nitride such as Zr oxide or Hf oxide, a dielectric constant of which is sufficiently larger than that of silicon nitride film, is used as a base material; and into which a proper amount of high-valence substance with a valence higher by two or more than that of the metal of the base material (i.e., the valence is six or more) is added, in order to generate therein a trapping level allowing electrons to enter/exit.
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Koichi Muraoka
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Takakura Shigeo
Satoshi Kono
Makoto Nakamura
Yoshihiro Fukuhara
Takashi Mine
Toshio Shirane
Sadao Muramatsu
Nobuhisa Nogawa
Kocho Chojiro
Naoki Kono
Katsu Sunagawa
Morisezo Iseki
Tatsushi Sato
Takashi Okada
Mihoko Horiuchi
Takenori Masanori