Title:
光学活性ジニッケル錯体及びそれを触媒とする光学活性アミンの製造方法
Document Type and Number:
Japanese Patent JP5382350
Kind Code:
B2
Abstract:
There is provided a novel optically active dinickel complex and/or a production method of an optically active amine by an asymmetric Mannich reaction using the dinickel complex as a catalyst. An optically active dinickel complex of Formula (I) or Formula (I'):
[where R 0 , R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 are each independently a hydrogen atom, a halogen atom, a C 1-10 alkyl group or a C 1-10 alkoxy group, etc., R 2 and R 3 together form, together with a benzene ring bonded to them, a naphthalene ring, etc. A novel production method of an optically active amine by an asymmetric Mannich reaction using the dinickel complex as a catalyst.
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Inventors:
Masakatsu Shibasaki
Shigeki Matsunaga
Chen Shika
Shigeki Matsunaga
Chen Shika
Application Number:
JP2009545432A
Publication Date:
January 08, 2014
Filing Date:
December 10, 2008
Export Citation:
Assignee:
Nissan Chemical Industry Co., Ltd.
International Classes:
C07C251/24; C07B53/00; C07B61/00; C07C269/00; C07C269/06; C07C271/22; C07D307/33; C07D307/54; C07D333/24; C07F15/04
Foreign References:
| WO2007011910A2 | 2007-01-25 | |||
| WO2007011910A2 | 2007-01-25 |
Other References:
JPN6013035165; Ｊ． Ａｍ． Ｃｈｅｍ． Ｓｏｃ． １２９（１６）, 2007, ｐ．４９００-４９０１
JPN6013035167; Ｂｕｌｌ． Ｃｈｅｍ． Ｓｏｃ． Ｊｐｎ． ７７（３）, 2004, ｐ．５６１-５６８
JPN6013035169; Ｂｕｌｌ． Ｃｈｅｍ． Ｓｏｃ． Ｊｐｎ． ７６（２）, 2003, ｐ．３２７-３３４
JPN6013035171; Ｊ． Ｏｒｇ． Ｃｈｅｍ． ６８（５）, 2003, ｐ．１９７３-１９８１
JPN6013035182; Ｈｅｌｖｅｔｉｃａ Ｃｈｉｍｉｃａ Ａｃｔａ ８２（１）, 1999, ｐ．１２５-１３７
JPN6013035173; Ｊ． Ａｍ． Ｃｈｅｍ． Ｓｏｃ． １３０（７）, 2008, ｐ．２１７０-２１７１
JPN6013035175; Ｏｒｇａｎｉｃ Ｌｅｔｔｅｒｓ １０（１５）, 2008, ｐ．３２３９-３２４２
JPN6013035177; 有機合成シンポジウム講演要旨集 ９３, 2008, ｐ．１３-１６
JPN6013035179; 日本薬学会年会要旨集 １２８（２）, 2008, ｐ．３１
JPN6013035180; 日本薬学会年会要旨集 １２８（２）, 2008, ｐ．１７４
JPN6013035181; 日本化学会講演予稿集 ８８（１）, 2008, ｐ．Ａ-１６
JPN6013035165; Ｊ． Ａｍ． Ｃｈｅｍ． Ｓｏｃ． １２９（１６）, 2007, ｐ．４９００-４９０１
JPN6013035167; Ｂｕｌｌ． Ｃｈｅｍ． Ｓｏｃ． Ｊｐｎ． ７７（３）, 2004, ｐ．５６１-５６８
JPN6013035169; Ｂｕｌｌ． Ｃｈｅｍ． Ｓｏｃ． Ｊｐｎ． ７６（２）, 2003, ｐ．３２７-３３４
JPN6013035171; Ｊ． Ｏｒｇ． Ｃｈｅｍ． ６８（５）, 2003, ｐ．１９７３-１９８１
JPN6013035182; Ｈｅｌｖｅｔｉｃａ Ｃｈｉｍｉｃａ Ａｃｔａ ８２（１）, 1999, ｐ．１２５-１３７
JPN6013035173; Ｊ． Ａｍ． Ｃｈｅｍ． Ｓｏｃ． １３０（７）, 2008, ｐ．２１７０-２１７１
JPN6013035175; Ｏｒｇａｎｉｃ Ｌｅｔｔｅｒｓ １０（１５）, 2008, ｐ．３２３９-３２４２
JPN6013035177; 有機合成シンポジウム講演要旨集 ９３, 2008, ｐ．１３-１６
JPN6013035179; 日本薬学会年会要旨集 １２８（２）, 2008, ｐ．３１
JPN6013035180; 日本薬学会年会要旨集 １２８（２）, 2008, ｐ．１７４
JPN6013035181; 日本化学会講演予稿集 ８８（１）, 2008, ｐ．Ａ-１６
JPN6013035167; Ｂｕｌｌ． Ｃｈｅｍ． Ｓｏｃ． Ｊｐｎ． ７７（３）, 2004, ｐ．５６１-５６８
JPN6013035169; Ｂｕｌｌ． Ｃｈｅｍ． Ｓｏｃ． Ｊｐｎ． ７６（２）, 2003, ｐ．３２７-３３４
JPN6013035171; Ｊ． Ｏｒｇ． Ｃｈｅｍ． ６８（５）, 2003, ｐ．１９７３-１９８１
JPN6013035182; Ｈｅｌｖｅｔｉｃａ Ｃｈｉｍｉｃａ Ａｃｔａ ８２（１）, 1999, ｐ．１２５-１３７
JPN6013035173; Ｊ． Ａｍ． Ｃｈｅｍ． Ｓｏｃ． １３０（７）, 2008, ｐ．２１７０-２１７１
JPN6013035175; Ｏｒｇａｎｉｃ Ｌｅｔｔｅｒｓ １０（１５）, 2008, ｐ．３２３９-３２４２
JPN6013035177; 有機合成シンポジウム講演要旨集 ９３, 2008, ｐ．１３-１６
JPN6013035179; 日本薬学会年会要旨集 １２８（２）, 2008, ｐ．３１
JPN6013035180; 日本薬学会年会要旨集 １２８（２）, 2008, ｐ．１７４
JPN6013035181; 日本化学会講演予稿集 ８８（１）, 2008, ｐ．Ａ-１６
JPN6013035165; Ｊ． Ａｍ． Ｃｈｅｍ． Ｓｏｃ． １２９（１６）, 2007, ｐ．４９００-４９０１
JPN6013035167; Ｂｕｌｌ． Ｃｈｅｍ． Ｓｏｃ． Ｊｐｎ． ７７（３）, 2004, ｐ．５６１-５６８
JPN6013035169; Ｂｕｌｌ． Ｃｈｅｍ． Ｓｏｃ． Ｊｐｎ． ７６（２）, 2003, ｐ．３２７-３３４
JPN6013035171; Ｊ． Ｏｒｇ． Ｃｈｅｍ． ６８（５）, 2003, ｐ．１９７３-１９８１
JPN6013035182; Ｈｅｌｖｅｔｉｃａ Ｃｈｉｍｉｃａ Ａｃｔａ ８２（１）, 1999, ｐ．１２５-１３７
JPN6013035173; Ｊ． Ａｍ． Ｃｈｅｍ． Ｓｏｃ． １３０（７）, 2008, ｐ．２１７０-２１７１
JPN6013035175; Ｏｒｇａｎｉｃ Ｌｅｔｔｅｒｓ １０（１５）, 2008, ｐ．３２３９-３２４２
JPN6013035177; 有機合成シンポジウム講演要旨集 ９３, 2008, ｐ．１３-１６
JPN6013035179; 日本薬学会年会要旨集 １２８（２）, 2008, ｐ．３１
JPN6013035180; 日本薬学会年会要旨集 １２８（２）, 2008, ｐ．１７４
JPN6013035181; 日本化学会講演予稿集 ８８（１）, 2008, ｐ．Ａ-１６
Attorney, Agent or Firm:
Calyx
Miyazaki Yoshio
Tsutomu Kato
Kyoko Oyama
Miyazaki Yoshio
Tsutomu Kato
Kyoko Oyama