Title:
不飽和有機化合物の製造方法
Document Type and Number:
Japanese Patent JP5446436
Kind Code:
B2
Abstract:
A method for producing an unsaturated organic compound represented by the formula (3):
(Y 1 ) m-1 -R 1 -R 2 -(Y 2 ) n-1 (3)
wherein Y 1 represents R 2 or X 1 , and Y 2 represents R 1 or B (X 2 ) 2 , which comprises reacting a compound represented by the formula (1) :
R 1 (X 1 ) m (1)
wherein R 1 represents an aromatic group or the like, X 1 represents a leaving group and m represents 1 or 2, with a compound represented by the formula (2):
R 2 {B(X 2 ) 2 } n (2)
wherein R 2 represents an aromatic group or the like, X 2 represents a hydroxyl group or the like, and n represents 1 or 2,
in the presence of
(a) a nickel compound selected from a nickel carboxylate, nickel nitrate and a nickel halide,
(b) a phosphine compound such as 1,4-bis(dicyclohexylphosphino)butane,
(c) an amine selected from a primary amine and a diamine such as N,N,N',N'-tetramethyl-1,2-ethanediamine, and
(d) an inorganic base.
Inventors:
Taku Asami
Taku Kamikawa
Taku Kamikawa
Application Number:
JP2009113359A
Publication Date:
March 19, 2014
Filing Date:
May 08, 2009
Export Citation:
Assignee:
Sumitomo Chemical Co., Ltd.
International Classes:
C07C1/32; C07C15/14; C07C15/27; C07C17/263; C07C25/18; C07C41/30; C07C43/205; C07C45/68; C07C47/546; C07C209/68; C07C211/45; C07C253/30; C07C255/50; C07D215/06; C07D333/08; C07B61/00
Domestic Patent References:
| JP2006305558A | ||||
| JP2005008578A | ||||
| JP2004189599A | ||||
| JP2006306758A | ||||
| JP2004091467A |
Attorney, Agent or Firm:
Toru Nakayama
Toru Sakamoto
Toru Sakamoto