Title:
遷移金属触媒作用を用いてハロゲン化アリール、ハロゲン化ヘテロアリール、ハロゲン化アルキル、およびハロゲン化アルケンをアリル化およびビニル化する方法
Document Type and Number:
Japanese Patent JP5540117
Kind Code:
B2
Abstract:
What is described is a process for preparing organic compounds of the general formula (I) R—R′ (I) by converting a corresponding compound of the general formula (II) R—X (II) in which X is fluorine, chlorine, bromine or iodine to an organomagnesium compound of the general formula (III) [M+]n[RmMgXkY1] (III) wherein compounds of the formula (III) are reacted with a compound of the general formula (IV) characterized in that the reaction of (III) with (IV) is performed in the presence of a) catalytic amounts of an iron compound, based on the compound of the general formula (II), and optionally in the presence of b) a nitrogen-, oxygen- and/or phosphorus-containing additive in a catalytic or stoichiometric amount, based on the compound of the general formula (II).
Inventors:
Matthias Gotta
Bernd Wilhelm Renemann
Valdemar Maximilian Zaplik
Matthias Meyer
Axel Jacobi von Vangeline
Bernd Wilhelm Renemann
Valdemar Maximilian Zaplik
Matthias Meyer
Axel Jacobi von Vangeline
Application Number:
JP2012552337A
Publication Date:
July 02, 2014
Filing Date:
February 01, 2011
Export Citation:
Assignee:
Saltigo Gamebecher
International Classes:
C07C1/32; C07C11/02; C07C15/44; C07C15/50; C07C15/60; C07C17/26; C07C22/08; C07C25/24; C07C41/30; C07C43/215; C07C67/343; C07C69/618; C07C69/76; C07C209/68; C07C211/48; C07C253/30; C07C255/50; C07B61/00
Domestic Patent References:
| JP2000239192A | ||||
| JP2010105985A | ||||
| JP2007119379A |
Foreign References:
| US20030220498 |
Other References:
KARLSTROEM,FERROCENYL THIOLATES AS LIGANDS IN THE ENANTIOSELECTIVE COPPER-CATALYZED SUBSTITUTION OF 以下備考,SYNLETT,2001年 1月20日,P923-926,ALLYLIC ACETATES WITH GRIGNARD REAGENTS
Attorney, Agent or Firm:
Yasuhiko Murayama
Masatake Shiga
Takashi Watanabe
Shinya Mitsuhiro
Masatake Shiga
Takashi Watanabe
Shinya Mitsuhiro