Title:
三座配位子ロジウム錯体、置換アセチレン重合開始剤及びそれを用いた置換ポリアセチレン誘導体の製造方法
Document Type and Number:
Japanese Patent JP5797497
Kind Code:
B2
Inventors:
Fumio Mita
Masashi Shiotsuki
Natsuhiro Sano
Masashi Shiotsuki
Natsuhiro Sano
Application Number:
JP2011186600A
Publication Date:
October 21, 2015
Filing Date:
August 29, 2011
Export Citation:
Assignee:
Nippon Chemical Industry Co., Ltd.
Kyoto University
Kyoto University
International Classes:
C07F19/00; C07C43/168; C07C211/27; C08F4/80; C08F38/00
Domestic Patent References:
| JP7102012A | ||||
| JP2010111796A | ||||
| JP2005047837A |
Other References:
尾西尚弥 他,高分子学会予稿集(CD-ROM),2011年 5月10日,vol.60 no.1 Disk1,page.RONNBUNNO.1PB034
Nishimura, T. et al,Asymmetric Polymerization of Achiral Arylacetylenes Giving Helical Polyacetylenes in the Presence of a Rhodium Catalyst with a C2-Symmetric Tetrafluorobenzobarrelene Ligand,Organometallics,2009年,28(16),pp.4890-4893
Aoki, T. et al,Helix-sence-selective Polymerizaition of Phenylacetylene Having Two Hydroxy Groups Using a Chiral Catalytic System,Journal of the American Chemical Society,2003年,125(21),pp.6346-6347
Koridze, A. A. et al,Norbornadiene complexes of transition metals. III. Stereospecificity in the generation of cationic complexes [Rh(2,3,8:5,6-η-C7H7CHR)(η-C5H5)]+ (R = Me, Ph, ferrocenyl), and molecular structure of [Rh(2,3,8:5,6-η-C7H7CH2)(η-C5H5)]+PF6-,Journal of Organometallic Chemistry ,1981年,206(3),pp.373-391
Ojima, I.; Vu, A. T.; Bonafoux, D.,Product class 5: organometallic complexes of rhodium,Science of Synthesis,2002年,1,531-616
Zagorevskii, D. V. et al,Mass spectrometry of transition metal π-complexes. 40. (η4-Norbornadiene)(η5-cyclopentadienyl)rhodium derivatives,Organic Mass Spectrometry ,1993年,28(4),463-9
Sato, T. et al,Role of chiral amine cocatalysts in the helix-sense-selective polymerization of a phenylacetylene using a catalytic system,Polymer,2004年,45(24),8109-8114
Nishimura, T. et al,Asymmetric Polymerization of Achiral Arylacetylenes Giving Helical Polyacetylenes in the Presence of a Rhodium Catalyst with a C2-Symmetric Tetrafluorobenzobarrelene Ligand,Organometallics,2009年,28(16),pp.4890-4893
Aoki, T. et al,Helix-sence-selective Polymerizaition of Phenylacetylene Having Two Hydroxy Groups Using a Chiral Catalytic System,Journal of the American Chemical Society,2003年,125(21),pp.6346-6347
Koridze, A. A. et al,Norbornadiene complexes of transition metals. III. Stereospecificity in the generation of cationic complexes [Rh(2,3,8:5,6-η-C7H7CHR)(η-C5H5)]+ (R = Me, Ph, ferrocenyl), and molecular structure of [Rh(2,3,8:5,6-η-C7H7CH2)(η-C5H5)]+PF6-,Journal of Organometallic Chemistry ,1981年,206(3),pp.373-391
Ojima, I.; Vu, A. T.; Bonafoux, D.,Product class 5: organometallic complexes of rhodium,Science of Synthesis,2002年,1,531-616
Zagorevskii, D. V. et al,Mass spectrometry of transition metal π-complexes. 40. (η4-Norbornadiene)(η5-cyclopentadienyl)rhodium derivatives,Organic Mass Spectrometry ,1993年,28(4),463-9
Sato, T. et al,Role of chiral amine cocatalysts in the helix-sense-selective polymerization of a phenylacetylene using a catalytic system,Polymer,2004年,45(24),8109-8114
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