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Title:
2,3,6−トリメチルフェノールの酸化による2,3,5−トリメチルベンゾキノンの製造方法
Document Type and Number:
Japanese Patent JP6561049
Kind Code:
B2
Abstract:
The invention relates to a method for producing 2,3,5-trimethyl benzoquinone or a compound containing 2,3,5-trimethyl benzoquinone, the method comprising the following steps: Oxidation of 2,3,6-trimethylphenol with oxygen or an oxygen-containing gas in a two-or multi-phase reaction medium in the presence of a catalyst or catalyst system containing at least one copper (II)-halide to a mixture containing 2,3,5-trimethyl benzoquinone, characterized in that the reaction medium contains water and at least one secondary aliphatic acyclic alcohol having 6 or more, preferably 7 or more, carbon atoms.

Inventors:
Dane, Richard
Claus, Michael
Martin, Dane
Danz, Manuel
Teres, joaquin enrique
Application Number:
JP2016522475A
Publication Date:
August 14, 2019
Filing Date:
June 25, 2014
Export Citation:
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Assignee:
BASF SE
International Classes:
C07C46/08; C07C50/04
Domestic Patent References:
JP61040239A
JP2264739A
JP62070337A
JP2174744A
JP63280040A
JP63017842A
JP60255746A
JP60255745A
Foreign References:
CN102108047A
CN1986513A
Other References:
SHIMIZU, M.,Synthesis of Alkyl Substituted p-Benzoquinones from the Corresponding Phenols Using Molecular Oxygen Catalyzed by Copper(II) Chloride-Amine Hydrochloride Systems,BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,1992年,Vol. 65, No.6,1522-1526
Attorney, Agent or Firm:
Yusuke Hiraki
Satoshi Fujita
Eiichi Arai
Natsuo Tanaka
Naoko Kikuta