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Document Type and Number:
Japanese Patent JPH0521914
Kind Code:
B2
Abstract:
The novel complex of the formula I (I) can be produced for example by electrochemical oxidation of 2-fluoro-5,6,11,12-tetraselenotetracene in the presence of an inert organic solvent and a bromide-containing electrolyte. The novel 2-fluoro-5,6,11,12-tetraselenotetracene can for its part be produced by reacting 2,3-naphthalenedicarboxylic anhydride, in the presence of a Friedel-Crafts catalyst, with fluorobenzene to 2-(4-fluorobenzoyl)-naphthalene-3-carboxylic acid; cyclizing this to 2-fluoro-5,12-naphthacenequinone; reducing the 2-fluoro-5,12-naphthacenequinone to 2-fluorotetracene; reacting the 2-fluorotetracene with sulfuryl chloride to 2-fluoro-5,11- or 2-fluoro-6,12-dichlorotetracene; and finally reacting the last-mentioned at elevated temperature with selenium to obtain 2-fluoro-5,6,11,12-tetraselenotetracene. The complex of the formula I is metallically conducting, and is distinguished by a stable metallic phase down to at least 5 DEG K. It can be used for example as an organic conductor element.

Inventors:
BURUNO HIRUTEI
KAARU UE MAIYAA
GURETEI RIISU
Application Number:
JP20925883A
Publication Date:
March 25, 1993
Filing Date:
November 09, 1983
Export Citation:
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Assignee:
CIBA GEIGY
International Classes:
C07C17/00; C07C17/12; C07C25/18; C07C25/22; C07C45/00; C07C50/22; C07C50/24; C07C51/00; C07C65/32; C07C65/34; C07C67/00; C07D345/00; C07D517/06; G03C1/73; G03F7/029; H01B1/12; H01G4/008; H01G9/04; H01G9/045; H01M4/60; H01M4/66



 
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