Title:
【発明の名称】電子受容体組成物
Document Type and Number:
Japanese Patent JPH09501432
Kind Code:
A
Abstract:
Stable electron acceptor compositions are composed of a plurality of pillared metal complexes disposed on a supporting substrate. At least one Group VIII metal at zero valence is entrapped within this matrix. The complexes comprise from one to about 100 units of the formula: -(Y1O3-Z-Y2O3)Me1- Y1 and Y2 being phosphorus or arsenic; Z being a divalent group which reversibly forms a stable reduced form and contains two conjugated cationic centers having a negative E DEG red value; and Me1 being a trivalent or tetravalent metal of Group III, IVA, or IVB having an atomic number of at least 21 or a lanthanide. The units are bound to the substrate through a divalent linking group. Counter anions balance the charge of Z. The compositions can be used in the decomposition of water to yield hydrogen gas, the sensing of oxygen, and as catalysts.
Inventors:
Thompson, Mark, Yi.
Snovar, jonathan, lee
Vermoilen, Raleigh, Anne
Snovar, jonathan, lee
Vermoilen, Raleigh, Anne
Application Number:
JP50647995A
Publication Date:
February 10, 1997
Filing Date:
August 09, 1994
Export Citation:
Assignee:
The Trustees of Princeton University
Thompson, Mark, Yi.
Snovar, jonathan, lee
Vermoilen, Raleigh, Anne
Thompson, Mark, Yi.
Snovar, jonathan, lee
Vermoilen, Raleigh, Anne
International Classes:
C07F7/00; B01J23/42; B01J29/04; B01J31/02; B01J31/16; B01J31/18; B01J35/00; B01J37/02; C01B3/04; C01B15/029; C07C2/00; C07F9/58; C08F8/44; C08F30/02; C08F30/04; B01J21/08; C08F230/02; C08F230/04; (IPC1-7): C07F9/58; C01B3/04
Attorney, Agent or Firm:
Mikio Hatta (1 outside)