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Title:
【発明の名称】陽イオン固体電解質
Document Type and Number:
Japanese Patent JPS6050727
Kind Code:
B2
Abstract:
PURPOSE:A cation solid electrolyte, consisting of an alkali metallic titanate of the hollandite type structure, expressed by a specific general formula, and having a very high electric conductivity. CONSTITUTION:A cation solid electrolyte expressed by the formula (A is alkali metal; B is Mg, Ni, CoII, Zn, Cu, Al, Fe, Cr, CoIII or Ga; X and Y are 0.5-3 respectively; Z is 5-8). Preferably, A is K or a solid solution of K and Li or K and Na, and B is Mg or Al. The electric conductivity is reduced if X and Y are beyond the range described above. Althrough the electric conductivity is obtained from any shape of the electrolyte if crystalline, a crystal in which a plane perpendicular to the crystallographic C axis is grown is most preferred. The crsytal can be prepared by the calcining or melting method, but the flux method using potassium molybdate, etc. as a fulx is preferred.

Inventors:
FUJIKI YOSHINORI
OOHACHI TADASHI
ONODA YOSHITO
WATANABE JUN
Application Number:
JP6473080A
Publication Date:
November 09, 1985
Filing Date:
May 16, 1980
Export Citation:
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Assignee:
KAGAKU GIJUTSUCHO MUKIZAISHITSU KENKYUSHOCHO
International Classes:
H01M6/18; C01G23/00; C30B29/32; H01B1/06; H01M8/10; H01M10/39; (IPC1-7): C01G23/00; C30B29/32; H01M6/18; H01M8/10; H01M10/39