Title:
α（１→４）グリコシド環状多量体及びその製造方法
Document Type and Number:
Japanese Patent JP6749644
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide: a method of chemically synthesizing α(1→4) glycoside cyclic trimers and tetramers; and α(1→4) glycoside cyclic trimers and tetramers that have not been synthesized before.SOLUTION: The present invention provides α(1→4) glycoside cyclic polymers represented by general formula (A) [where Rrepresents a hydrogen atom or a hydroxy protecting group; Rand Reither each represent a hydrogen atom or are linked to each other to represent a specific crosslinking group formed together with the carbon atoms linked to them; and m represents an integer of 3 or 4].SELECTED DRAWING: None
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Inventors:
Hidetoshi Yamada
Application Number:
JP2017038585A
Publication Date:
September 02, 2020
Filing Date:
March 01, 2017
Export Citation:
Assignee:
School corporation Kansai Gakuin
International Classes:
C07H9/02
Domestic Patent References:
| JP2013166740A |
Foreign References:
| US6562600 | ||||
| WO2014125967A1 |
Other References:
ADEUYA, A. et al.,Enumeration of carbohydrate hydroxyl groups by silylation and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry,Rapid Communications in Mass Spectrometry,2007年,21(13),pp. 2095-2100
NAKAGAWA, T. et al.,The Stereoselective Synthesis of Cyclomaltopentaose. A Novel Cyclodextrin Homologue with D.P. Five.,Tetrahedron Letters,1994年,35(12),pp. 1921-1924
IMMEL, S. et al.,Molecular Modeling of Saccharides, 6. Small-Ring Cyclodextrins: Their Geometries and Hydrophobic Topographies,Liebigs Annalen,1995年,(6),pp. 929-942
MAITI, K. et al.,Synthesis and Structure of Cyclic Trisaccharide with Expanded Glycosidic Linkages,Journal of Organic Chemistry,2016年,81(11),pp. 4616-4622
LIPKIND, G. M. et al.,Computer-assisted analysis of the structure of regular branched polysaccharides containing 2,3-disubstituted rhamnopyranose and mannopyranose residues on the basis of 13C NMR data,Carbohydrate Research,1992年,237,pp. 11-22
BIELY, P. et al.,Enzymic α-galactosylation of a cyclic glucotetrasaccharide derived from alternan,Carbohydrate Research,2001年,332(3),pp. 299-303
NAKAGAWA, T. et al.,The Stereoselective Synthesis of Cyclomaltopentaose. A Novel Cyclodextrin Homologue with D.P. Five.,Tetrahedron Letters,1994年,35(12),pp. 1921-1924
IMMEL, S. et al.,Molecular Modeling of Saccharides, 6. Small-Ring Cyclodextrins: Their Geometries and Hydrophobic Topographies,Liebigs Annalen,1995年,(6),pp. 929-942
MAITI, K. et al.,Synthesis and Structure of Cyclic Trisaccharide with Expanded Glycosidic Linkages,Journal of Organic Chemistry,2016年,81(11),pp. 4616-4622
LIPKIND, G. M. et al.,Computer-assisted analysis of the structure of regular branched polysaccharides containing 2,3-disubstituted rhamnopyranose and mannopyranose residues on the basis of 13C NMR data,Carbohydrate Research,1992年,237,pp. 11-22
BIELY, P. et al.,Enzymic α-galactosylation of a cyclic glucotetrasaccharide derived from alternan,Carbohydrate Research,2001年,332(3),pp. 299-303
Attorney, Agent or Firm:
Patent Business Corporation Saegusa International Patent Office