Title:
1*22DIPHENYLCYCLOHEXEE11ENEE44 CARBOXYLATE DERIVATIVES PROCESS FOR PREPARING SAME AND PLANT GROWTH ADJUSTING AGENT CONTAINING SAME
Document Type and Number:
Japanese Patent JPS5223050
Kind Code:
A
Abstract:
Procedure for the preparation of a 1,2-diphenyl-cyclohex-l-en-4-carboxylic acid derivative of the formula I **(See formula)** in which U, V, W, X, Y and Z stand for, independently of one another, hydrogen, halogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, NO2, CF3, COOH, CN, OH, S03H, NH2, -NH (< C1-C4 alkyl) or -N (C1-C4 alkyl) 2, although U and X may each additionally signify an unsubstituted phenyl radical, and represents one of the two groups - OR ° or -SR, where R ° means - hydrogen or - the cation of a base **(See formula)** in which M represents an alkaline, alkaline earth cation of Fe, Cu, Zn, Mn or Ni or an ammonium radical **(See formula)** and takes into account, as an integer 1, 2 or 3, the valence of the cation, while R2, R3 and R4 independently of one another they represent hydrogen, benzyl or a radical (optionally substituted by -OH, -NH2 or C1-C4 alkoxy) of C1-C8 alkyl O well - represent; and R means: - a C1-C18 alkyl radical, unsubstituted or possibly substituted by halogen, by nitro, by cyano, by C1-C8 alkoxy, by C2-C8 alkoxyalkyl, by C3-C6 alkenyloxy, by C1- alkylthio C8, by C2-C8 alkanoyl, by C2-C8 acyloxy, by C2-C8 alkoxycarbonyl or by carbamoyl; bis- (C2-C8-alkyl-amino, tris- (C1-C4-alkyl) -ammonium, C3-C8-cycloalkyl, C3-C8-cycloalkenyl or optionally also by a radical (unsubstituted or uni- or pluri-substituted by in turn by halogen, by C1-C4 alkyl or by C1-C4 alkoxy) phenyl, phenoxy or heterocyclic pentagonal or hexagonal with 1 to 3 heteroatoms; - an unsubstituted C3-C18 alkenyl radical, or substituted one to four times by halogen or once by phenyl or methoxycarbonyl; - a C3-C8 alkynyl radical; - a C3-C12 cycloalkyl radical, optionally substituted by halogen or by C1-C4 alkyl; - a C3-C8 cycloalkenyl radical; - a phenyl radical, unsubstituted or substituted by halogen, by C1-C4 alkyl, by C1-C4 alkoxy, by C1-C4 alkylthio, by NO2, by CF3, by COOH, by CN, by OH, by S03H, by NH2, by -NH (C1-C4 alkyl) or by -N (C1-C4 alkyl) 2 one or more times; - or a pentagonal to hexagonal heterocyclic ring with 1 to 3 heteroatoms, which constitutes the active component, for together with appropriate vehicle materials, the formation of agents to influence the growth of plants, characterized in that in their performance a reaction is verified addition of acrylonitrile or an acrylic acid derivative of formula II **(See formula)** in which G has the same meaning as for formula I, to a diene of formula III **(See formula)** optionally formed as an intermediate compound from a diol of formula IIIa **(See formula)** and consecutive transformation, in the usual way, of the nitrile group introduced by using acrylonitrile in the carboxylic group or the ester group -CO-G according to the definition above. (Machine-translation by Google Translate, not legally binding)
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Inventors:
BERENA RAANIO
BERUNAA FUEERII
RORUFU SHIYUURUTAA
BERUNAA FUEERII
RORUFU SHIYUURUTAA
Application Number:
JP9763276A
Publication Date:
February 21, 1977
Filing Date:
August 16, 1976
Export Citation:
Assignee:
CIBA GEIGY AG
International Classes:
A01N37/08; A01N37/10; A01N37/12; C07C61/16; A01N37/34; A01N37/36; A01N37/38; A01N37/44; A01N37/46; A01N37/48; A01N41/06; A01N43/04; C07C51/00; C07C61/39; C07C61/40; C07C62/06; C07C62/12; C07C62/34; C07C67/00; C07C201/00; C07C205/56; C07C205/57; C07C229/46; C07C229/54; C07C253/00; C07C255/32; C07C255/57; C07C301/00; C07C303/22; C07C309/32; C07C313/00; C07C323/62; C07C323/66; C07C325/00; C07C327/22; C07C327/24; C07D211/46; C07D213/30; C07D295/088; C07D307/12; C07D309/06; C07D309/12; C07D333/16; C07F1/00; C07F3/00; (IPC1-7): A01G1/00; C07C63/33