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Title:
1,3-butadiene separator and separation method using the separator
Document Type and Number:
Japanese Patent JP6305405
Kind Code:
B2
Abstract:
A separating material superior to conventional separating materials, and a separation method are provided, with which 1,3-butadiene is selectively separated and recovered from a mixed gas including 1,3-butadiene and C4 hydrocarbons other than 1,3-butadiene. A metal complex, which comprises a dicarboxylic acid compound (I) (see (I) below) represented by general formula (I), an ion of a metal such as beryllium, and a bipyridyl compound (II) represented by general formula (II), namely L-Z-L (II) (see (L) below), is characterized by including, as the dicarboxylic acid compound (I), at least two different dicarboxylic acid compounds (I). The metal complex is used as a 1,3-butadiene separating material. Formula (I) L is represented by any of the compounds below. Formula (L).

Inventors:
Keisuke Kishida
Watanabe Kenhiro
Yoshikuni Okumura
Application Number:
JP2015528205A
Publication Date:
April 04, 2018
Filing Date:
July 01, 2014
Export Citation:
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Assignee:
SHOWA DENKO K.K.
International Classes:
B01D53/04; B01J20/22; B01D53/047; B01J20/28; B01J20/30; B01J20/34; C07C7/12; C07C11/20; C07C63/15; C07C205/57; C07C309/58; C07D213/80
Domestic Patent References:
JP201168631A
JP2012180322A
JP201151949A
JP201231161A
JP2012193122A
JP2010180201A
Foreign References:
WO2013024761A1
Attorney, Agent or Firm:
Atsushi Aoki
Takashi Ishida
Tetsuji Koga
Satoshi Deno
Atsushi Ebiya
Masatoshi Takahashi
Naori Kota