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Title:
2,5-PYRROLE-CONTAINING SILOLE COMPOUND, SILOLE-PYRROLE COPOLYMER AND THEIR PRODUCTION
Document Type and Number:
Japanese Patent JP3114556
Kind Code:
B2
Abstract:

PURPOSE: To obtain both a 2,5-pyrrole-containing silole compound as a new πelectron conjugated organic compound useful as an optically functional material or its synthetic raw material and a silolepyrrole copolymer and to provide methods for producing the compound and the copolymer.
CONSTITUTION: This compound is shown by formula I (R1 to R5 are each the same or different 1-12C monofunctional hydrocarbon or H) such as 1,1-diethyl-2,5- bis(N-methyl-2-pyrrolyl)-3,4-diphenylsilole. The compound of formula I is obtained by a reaction equation of formula II (X is a halogen; Y is triorganosilyl, etc.). The compound of formula I is reacted with an organolithium compound and a triorganosilyl halide to give an intermediate, which is polymerized in the presence of an oxidizing agent and a palladium catalyst to give a silole-pyrrole copolymer.


Inventors:
Tamao, Kohei
Yamaguchi, Shigehiro
Application Number:
JP1995000079686
Publication Date:
December 04, 2000
Filing Date:
March 10, 1995
Export Citation:
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Assignee:
SHIN ETSU CHEM CO LTD
International Classes:
B01J23/44; B01J31/22; C07B61/00; C07F7/10; C08G77/48; C08G77/60; (IPC1-7): C07F7/10; C08G77/60
Other References:
”Chem.Commun.(Cambridge),”(1996)No.16,pages 1873−1874
Attorney, Agent or Firm:
小島 隆司