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Title:
天然カロチノイド生成物の合成のための4-クロロ-3-メチル-2-ブテニルフェニルサルファイド、ジ(4-クロロ-3-メチル-2-ブテニル)サルファイドおよびジ(4-クロロ-3-メチル-2-ブテニル)スルホンの調製方法
Document Type and Number:
Japanese Patent JP4903774
Kind Code:
B2
Abstract:
Disclosed is a method of preparing intermediates required for synthesis of natural carotenoid products using sulfone compounds, which is advantageous in terms of high preparation efficiency due to a relatively simple process. Specifically, there is provided the preparation method of 4-chloro-3-methyl-2-butenylphenylsulfide as a C5-unit compound for lengthening a carbon chain, and di4-chloro-3-methyl-2-butenylsulfide as a C10-unit compound for forming a central polyene moiety. In addition, di4-chloro-3-methyl-2-butenylsulfone as a selective oxide of the di4-chloro-3-methyl-2-butenylsulfide and a preparation method thereof are provided.

Inventors:
Gusanho
Yanze Doc
Kim john sue
Lee Jiyoung
Park Minsu
Application Number:
JP2008318524A
Publication Date:
March 28, 2012
Filing Date:
December 15, 2008
Export Citation:
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Assignee:
SK Holdings Co., Ltd.
Gusanho
International Classes:
C07C317/08; C07C403/22; C07B61/00; C07C17/16; C07C21/14; C07C29/64; C07C31/36; C07C315/02; C07C315/04; C07C317/14; C07C317/22; C07C319/14; C07C323/09; C07C323/05
Domestic Patent References:
JP48085532A
JP48085552A
JP52062231A
JP62063559A
JP2000063351A
JP2002529448A
Foreign References:
KR20020059202A
WO2001064630A1
Other References:
Journal of Organic Chemistry,1999年,64(21),p.8051-8053
Angewandte Chemie, International Edition,2001年,40(19),p.3627-3629
Attorney, Agent or Firm:
Patent Service Corporation Patent Office Sykes