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Title:
ACETYLENE DERIVATIVE, ITS PRODUCTION, LIQUID CRYSTAL COMPOSITION WITH THE SAME AS ACTIVE INGREDIENT AND LIQUID CRYSTAL ELEMENT USING THE COMPOSITION
Document Type and Number:
Japanese Patent JPH08143482
Kind Code:
A
Abstract:

PURPOSE: To obtain a new acetylene derivative excellent in quick response and ferroelectricity, thus useful as a material for light switching elements and liquid crystal display elements, etc.

CONSTITUTION: This compound, a new acetylene derivative, is expressed by formula I [R is H, F, trifluoromethyl, trifluoromethoxy, cyano, a R1-(cycloalkyl), R1-(cycloalkenyl), or R1-(O)m; R1 is a (halogen-substituted) 1-15C alkyl, alkenyl or alkynyl; (m) is 0 or 1; R2 is a (halogen-substituted) 1-15C alkyl, alkenyl. etc.; E is CH=CH or C=C; Z is H or F; A1 and A2 are each of formula II ((i) is 0-3), etc.; (r), (s) and (t) are each 0 or 1; 9n) is 0-8], e.g., 1-(4- decyloxyphenyl)-2-(4-(6-hydroxy-1-heptynyl)phenyl)acetylene. The compound of formula I is obtained, for example, by reaction between an ethynylbenzene derivative of formula III (D is a halogen, etc.) and a boron compound of formula IV (R3 is hydroxyl, etc.) in the presence of a basic substance.


Inventors:
FUJIMOTO YUKARI
MATSUMOTO TSUTOMU
MINAMII MASAYOSHI
Application Number:
JP28793194A
Publication Date:
June 04, 1996
Filing Date:
November 22, 1994
Export Citation:
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Assignee:
SUMITOMO CHEMICAL CO
International Classes:
C07D237/08; C07C13/28; C07C15/50; C07C22/08; C07C25/24; C07C33/28; C07C33/38; C07C33/48; C07C33/50; C07C41/30; C07C43/166; C07C43/178; C07C43/20; C07C43/205; C07C43/225; C07C67/343; C07C69/007; C07C69/63; C07C255/30; C07C255/49; C07C255/54; C07C255/55; C07D213/64; C07D237/12; C07D237/14; C07D237/24; C07D239/26; C07D239/30; C07D239/34; C07D239/74; C07D239/78; C07D239/80; C07D241/12; C07D241/16; C07D241/18; C07D241/24; C07D241/42; C07D241/44; C09K19/18; C09K19/32; C09K19/34; G09F9/35; (IPC1-7): C07C13/28; C07C15/50; C07C22/08; C07C25/24; C07C33/28; C07C33/38; C07C33/48; C07C33/50; C07C41/30; C07C43/166; C07C43/178; C07C43/20; C07C43/205; C07C43/225; C07C67/343; C07C69/007; C07C69/63; C07C255/30; C07C255/49; C07C255/54; C07C255/55; C07D213/64; C07D237/08; C07D237/12; C07D237/14; C07D237/24; C07D239/26; C07D239/30; C07D239/34; C07D239/74; C07D239/78; C07D239/80; C07D241/12; C07D241/16; C07D241/18; C07D241/24; C07D241/42; C07D241/44; C09K19/18; C09K19/32; C09K19/34; G09F9/35
Attorney, Agent or Firm:
Takashi Kuboyama (1 person outside)