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Title:
AQUEOUS POLYMER DISPERSION
Document Type and Number:
Japanese Patent JPH05202255
Kind Code:
A
Abstract:

PURPOSE: To obtain the title dispersion not discolored over a long period of time inclusive of a formed film by adding guanidine when a halogen-containing monomer mixture is subjected to radical emulsion polymn. to adjust the pH value of a generated aq. polymer dispersion to a specific range.

CONSTITUTION: A monomer mixture containing 10-100 wt.% of a halogen- containing monomer (e.g.; vinyl chloride) is polymerized in an aq. medium by a radical emulsion polymn. method and the pH value of the aq. phase of the generated aq. polymer dispersion is adjusted to 5-10 by adding guanidine and, at this time, guanidine is added before, during and/or after emulsion polymn. to obtain an aq. polymer dispersion. This dispersion and a film formed therefrom are not substantially discoloted even after long-term storage. The discoloration tendency of this aq. polymer dispersion is further reduced by adding 0.005-1 wt.% of an acting substance selected from glycerine, citric acid and the like to the monomer mixture.


Inventors:
HAINRITSUHI GURUUBERUTO
RORUFU DERUSHIYU
YOOZEFU NOITSUNAA
RAINAA FUNMERITSUHI
PEETAA YOOZEFU MARIA BUEE KURA
Application Number:
JP19680492A
Publication Date:
August 10, 1993
Filing Date:
July 23, 1992
Export Citation:
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Assignee:
BASF AG
International Classes:
C08F2/22; C08F2/24; C08F2/44; C08F14/00; C08F14/06; C08K13/02; C08L27/02; C08L27/06; (IPC1-7): C08F2/22; C08F2/44; C08L27/02
Attorney, Agent or Firm:
Toshio Yano (2 outside)



 
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