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Title:
BIS DINITROPHENYL METHYLPYRIDINIUM OR QUNIOLINIUM COMPOUND
Document Type and Number:
Japanese Patent JPS56145273
Kind Code:
A
Abstract:

NEW MATERIAL:Compounds of formula I [R1 is formula II, formula III (R3 is alkyl, aralkyl, allyl, 3-phenylallyl; X is alkyl, alkoxy, aryl, aryloxy, halogen, hydroxyl, H); Y is anionic functional group] or formula IV (R2 is formula V or formula VI).

EXAMPLE: 4-[Bis(2,4-dinitrophenyl)methyl]-1-ethylpyridinium chloride.

USE: Reagent for detecting ammonia: it has high sensitivity and keeps high sensitivity even in a dry or hydrophobic medium. Further, it shows high stability to light and heat.

PREPARATION: The reaction of a quaternary salt of methyl-substituted pyridine or quinoline with dinitrochlorobenzene is carried out in acetonitrile in the presence of triethylamine and the resultant product is isolated and made to react with an appropriate acid to give the compound of formula I.


Inventors:
UKAI TOSHINAO
KITAJIMA MASAO
Application Number:
JP4619880A
Publication Date:
November 11, 1981
Filing Date:
April 10, 1980
Export Citation:
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Assignee:
FUJI PHOTO FILM CO LTD
International Classes:
C07D215/12; C07D213/26; C09B11/26; C09B23/00; G01N31/00; G01N31/22; G01N33/52; (IPC1-7): C07D213/26; C07D215/12; C09B23/00; G01N31/22; G01N33/52