Title:
PRODUCTION OF DIARYLPHOSPHINOPYRIDINE
Document Type and Number:
Japanese Patent JP3139813
Kind Code:
B2
Abstract:
PURPOSE: To obtain a diarylphosphinopyridine useful for industry, etc., in a high yield without requiring a strictly purifying operation by allowing a triarylphosphine to react with an alkali metal and allowing the resultant alkali diarylphosphide to react with a pyridyl halide.
CONSTITUTION: A triarylphosphine is allowed to react with about 2 equiv. alkali metal such as lithium at -20 to +70°C in an aprotic solvent such as ether to produce an alkali diarylphosphide and an alkali aryl. The alkali aryl is selectively removed and the alkali diarylphosphide is allowed to react with about 1 equiv. properly substd. pyridyl halide such as 2-pyridyl halide based on 1 halogen group and the resultant diarylphosphinopyridine is separated to obtain the objective compd.
Inventors:
Peter Anton August Cruzenel
Jacoba, Catherina, Lucia, Johanna, Suikerbuik
Pieter Adrien Huelbrücket
Jacoba, Catherina, Lucia, Johanna, Suikerbuik
Pieter Adrien Huelbrücket
Application Number:
JP5879892A
Publication Date:
March 05, 2001
Filing Date:
February 13, 1992
Export Citation:
Assignee:
SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BESLOTEN VENNOOTSHAP
International Classes:
C07F9/50; C07F9/28; C07F9/58; (IPC1-7): C07F9/58
Domestic Patent References:
| JP63258889A | ||||
| JP63287788A | ||||
| JP649994A |
Other References:
【文献】日本化学会編 新実験化学講座12 有機金属化学,第431頁(丸善株式会社)昭和51年3月20日発行
Attorney, Agent or Firm:
Kazuho Kawarada