Title:
CATALYST COMPLEX WITH CARBENE LIGAND
Document Type and Number:
Japanese Patent JP2013099739
Kind Code:
A
Abstract:
To provide catalytic complexes with carbene ligands for use in a variety of olefin metathesis reactions.
The catalytic complexes include a metal atom having anionic ligands, at least one nucleophilic carbene ligand, and an alkylidene, vinylidene, or allenylidene ligand. The complexes are highly stable to air, moisture and thermal degradation. The complexes are designed to efficiently carry out a variety of olefin metathesis reactions.
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Inventors:
NOLAN STEVEN P
HUANG JINKUN
HUANG JINKUN
Application Number:
JP2012264339A
Publication Date:
May 23, 2013
Filing Date:
December 03, 2012
Export Citation:
Assignee:
UNIV OF NEW ORLEANS RES & TECHNOLOGY FOUNDATION INC
International Classes:
B01J31/24; B01J31/16; B01J31/22; C07C4/08; C07C13/20; C07D233/06; C07F9/50; C07F15/00; C07F19/00
Domestic Patent References:
| JPH11510807A | 1999-09-21 | |||
| JP2002510658A | 2002-04-09 | |||
| JP2003500412A | 2003-01-07 |
Foreign References:
| US5728839A | 1998-03-17 | |||
| US5312940A | 1994-05-17 | |||
| WO1997006185A1 | 1997-02-20 |
Other References:
JPN6009047244; ＨＥＲＲＭＡＮＮ， Ｗ．Ａ． ｅｔ ａｌ: 'Ｎ-Ｈｅｔｅｒｏｃｙｃｌｉｃ Ｃａｒｂｅｎｅｓ' ＡＮＧＥＷＡＮＤＴＥ ＣＨＥＭＩＥ． ＩＮＴＥＲＮＡＴＩＯＮＡＬ ＥＤＩＴＩＯＮ ｖｏｌ．３６, 1997, ｐ．２１６２-２１８７
JPN6009047252; ＤＵＳＳＥＬ， Ｒ． ｅｔ ａｌ: 'Ｉｓｏｃｙａｎｉｄｅ ａｒｅｎｅ-ｒｕｔｈｅｎｉｕｍ（ＩＩ） ｃｏｍｐｌｅｘｅｓ ａｎｄ ａｃｔｉｖａｔｉｏｎ ｏｆ ａｌｋｅｎｙｌａｃｅｔｙｌｅｎｅｓ： ｓｙｎｔｈｅｓｉｓ ａｎｄ ｃｈａｒａｃｔｅ' ＯＲＧＡＮＯＭＥＴＡＬＬＩＣＳ １０（９）, 1991, ｐ．３２８７-９１
JPN6009047274; ＷＥＳＫＡＭＰ，Ｔ． ｅｔ ａｌ: 'Ａ Ｎｏｖｅｌ Ｃｌａｓｓ ｏｆ Ｒｕｔｈｅｎｉｕｍ Ｃａｔａｌｙｓｔｓ ｆｏｒ Ｏｌｅｆｉｎ Ｍｅｔａｔｈｅｓｉｓ' Ａｎｇｅｗａｎｄｔｅ Ｃｈｅｍｉｅ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｅｄｉｔｉｏｎ Ｖｏｌ．３７， Ｎｏ．１８, 19981002, ｐ．２４９０ - ２４９３
JPN6009047259; ＷＥＳＫＡＭＰ Ｔ． ｅｔ ａｌ: 'ＨＩＧＨＬＹ ＡＣＴＩＶＥ ＲＵＴＨＥＮＩＵＭ ＣＡＴＡＬＹＳＴＳ ＦＯＲ ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ： ＴＨＥ ＳＹＮＥＲＧＹ ＯＦ Ｎ-ＨＥＴＥＲＯＣＹＣＬＩＣ ＣＡＲＢＥＮＥＳ ＡＮＤ' ＡＮＧＥＷＡＮＤＴＥ ＣＨＥＭＩＥ． ＩＮＴＥＲＮＡＴＩＯＮＡＬ ＥＤＩＴＩＯＮ ｖｏｌ．３８， Ｎｏ．１６, 19990806, ｐ．２４１６-２４１９
JPN6009047262; ＡＣＫＥＲＭＡＮＮ Ｌ． ｅｔ ａｌ: 'Ｒｕｔｈｅｎｉｕｍ ｃａｒｂｅｎｅ ｃｏｍｐｌｅｘｅｓ ｗｉｔｈ ｉｍｉｄａｚｏｌｉｎ-２-ｙｌｉｄｅｎｅ ｌｉｇａｎｄｓ ａｌｌｏｗ ｔｈｅ ｆｏｒｍａｔｉｏｎ ｏｆ ｔｅｔｒａｓｕｂｓｔｉｔｕｔｅ' ＴＥＴＲＡＨＥＤＲＯＮ ＬＥＴＴＥＲＳ ｖｏｌ．４０， Ｎｏ．２６, 19990625, ｐ．４７８７-４７９０
JPN6009047265; ＨＵＡＮＧ Ｊ． ｅｔ ａｌ: 'ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ-ＡＣＴＩＶＥ ＲＵＴＨＥＮＩＵＭ ＣＯＭＰＬＥＸＥＳ ＢＥＡＲＩＮＧ Ａ ＮＵＣＬＥＯＰＨＩＬＩＣＣＡＲＢＥＮＥ ＬＩＧＡＮＤ' ＪＯＵＲＮＡＬ ＯＦ ＴＨＥ ＡＭＥＲＩＣＡＮ ＣＨＥＭＩＣＡＬ ＳＯＣＩＥＴＹ ｖｏｌ．１２１， Ｎｏ．１２, 19990311, ｐ．２６７４-２６７８
JPN6009047269; ＳＣＨＯＬＬ Ｍ． ｅｔ ａｌ: 'ＳＹＮＴＨＥＳＩＳ ＡＮＤ ＡＣＴＩＶＩＴＹ ＯＦ Ａ ＮＥＷ ＧＥＮＥＲＡＴＩＯＮ ＯＦ ＲＵＴＨＥＮＩＵＭ-ＢＡＳＥＤ ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ ＣＡＴＡＬＹＳＴＳ ＣＯＯＲＤＩＮＡＴＥ' ＯＲＧＡＮＩＣ ＬＥＴＴＥＲＳ ｖｏｌ．１， Ｎｏ．６, 19990813, ｐ．９５３-９５６
JPN7009004188; ＦＵＲＳＴＮＥＲ， Ａ． ｅｔ ａｌ: 'Ｃａｔｉｏｎｉｃ Ｒｕｔｈｅｎｉｕｍ Ａｌｌｅｎｙｌｉｄｅｎｅ Ｃｏｍｐｌｅｘｅｓ ａｓ ａ Ｎｅｗ Ｃｌａｓｓ ｏｆ Ｐｅｒｆｏｒｍｉｎｇ Ｃａｔａｌｙｓｔｓ ｆｏｒ Ｒｉｎｇ Ｃｌｏｓｉｎｇ Ｍｅ' ＣＨＥＭＩＣＡＬ ＣＯＭＭＵＮＩＣＡＴＩＯＮＳ ｎｏ．１２, 19980621, ｐ．１３１５-１３１６
JPN6009047252; ＤＵＳＳＥＬ， Ｒ． ｅｔ ａｌ: 'Ｉｓｏｃｙａｎｉｄｅ ａｒｅｎｅ-ｒｕｔｈｅｎｉｕｍ（ＩＩ） ｃｏｍｐｌｅｘｅｓ ａｎｄ ａｃｔｉｖａｔｉｏｎ ｏｆ ａｌｋｅｎｙｌａｃｅｔｙｌｅｎｅｓ： ｓｙｎｔｈｅｓｉｓ ａｎｄ ｃｈａｒａｃｔｅ' ＯＲＧＡＮＯＭＥＴＡＬＬＩＣＳ １０（９）, 1991, ｐ．３２８７-９１
JPN6009047274; ＷＥＳＫＡＭＰ，Ｔ． ｅｔ ａｌ: 'Ａ Ｎｏｖｅｌ Ｃｌａｓｓ ｏｆ Ｒｕｔｈｅｎｉｕｍ Ｃａｔａｌｙｓｔｓ ｆｏｒ Ｏｌｅｆｉｎ Ｍｅｔａｔｈｅｓｉｓ' Ａｎｇｅｗａｎｄｔｅ Ｃｈｅｍｉｅ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｅｄｉｔｉｏｎ Ｖｏｌ．３７， Ｎｏ．１８, 19981002, ｐ．２４９０ - ２４９３
JPN6009047259; ＷＥＳＫＡＭＰ Ｔ． ｅｔ ａｌ: 'ＨＩＧＨＬＹ ＡＣＴＩＶＥ ＲＵＴＨＥＮＩＵＭ ＣＡＴＡＬＹＳＴＳ ＦＯＲ ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ： ＴＨＥ ＳＹＮＥＲＧＹ ＯＦ Ｎ-ＨＥＴＥＲＯＣＹＣＬＩＣ ＣＡＲＢＥＮＥＳ ＡＮＤ' ＡＮＧＥＷＡＮＤＴＥ ＣＨＥＭＩＥ． ＩＮＴＥＲＮＡＴＩＯＮＡＬ ＥＤＩＴＩＯＮ ｖｏｌ．３８， Ｎｏ．１６, 19990806, ｐ．２４１６-２４１９
JPN6009047262; ＡＣＫＥＲＭＡＮＮ Ｌ． ｅｔ ａｌ: 'Ｒｕｔｈｅｎｉｕｍ ｃａｒｂｅｎｅ ｃｏｍｐｌｅｘｅｓ ｗｉｔｈ ｉｍｉｄａｚｏｌｉｎ-２-ｙｌｉｄｅｎｅ ｌｉｇａｎｄｓ ａｌｌｏｗ ｔｈｅ ｆｏｒｍａｔｉｏｎ ｏｆ ｔｅｔｒａｓｕｂｓｔｉｔｕｔｅ' ＴＥＴＲＡＨＥＤＲＯＮ ＬＥＴＴＥＲＳ ｖｏｌ．４０， Ｎｏ．２６, 19990625, ｐ．４７８７-４７９０
JPN6009047265; ＨＵＡＮＧ Ｊ． ｅｔ ａｌ: 'ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ-ＡＣＴＩＶＥ ＲＵＴＨＥＮＩＵＭ ＣＯＭＰＬＥＸＥＳ ＢＥＡＲＩＮＧ Ａ ＮＵＣＬＥＯＰＨＩＬＩＣＣＡＲＢＥＮＥ ＬＩＧＡＮＤ' ＪＯＵＲＮＡＬ ＯＦ ＴＨＥ ＡＭＥＲＩＣＡＮ ＣＨＥＭＩＣＡＬ ＳＯＣＩＥＴＹ ｖｏｌ．１２１， Ｎｏ．１２, 19990311, ｐ．２６７４-２６７８
JPN6009047269; ＳＣＨＯＬＬ Ｍ． ｅｔ ａｌ: 'ＳＹＮＴＨＥＳＩＳ ＡＮＤ ＡＣＴＩＶＩＴＹ ＯＦ Ａ ＮＥＷ ＧＥＮＥＲＡＴＩＯＮ ＯＦ ＲＵＴＨＥＮＩＵＭ-ＢＡＳＥＤ ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ ＣＡＴＡＬＹＳＴＳ ＣＯＯＲＤＩＮＡＴＥ' ＯＲＧＡＮＩＣ ＬＥＴＴＥＲＳ ｖｏｌ．１， Ｎｏ．６, 19990813, ｐ．９５３-９５６
JPN7009004188; ＦＵＲＳＴＮＥＲ， Ａ． ｅｔ ａｌ: 'Ｃａｔｉｏｎｉｃ Ｒｕｔｈｅｎｉｕｍ Ａｌｌｅｎｙｌｉｄｅｎｅ Ｃｏｍｐｌｅｘｅｓ ａｓ ａ Ｎｅｗ Ｃｌａｓｓ ｏｆ Ｐｅｒｆｏｒｍｉｎｇ Ｃａｔａｌｙｓｔｓ ｆｏｒ Ｒｉｎｇ Ｃｌｏｓｉｎｇ Ｍｅ' ＣＨＥＭＩＣＡＬ ＣＯＭＭＵＮＩＣＡＴＩＯＮＳ ｎｏ．１２, 19980621, ｐ．１３１５-１３１６
Attorney, Agent or Firm:
Shinjiro Ono
Yasushi Kobayashi
Hiroyuki Tomita
Osamu Hoshino
Toyoji Matsuda
Yasushi Kobayashi
Hiroyuki Tomita
Osamu Hoshino
Toyoji Matsuda
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