CATALYST FOR (CO)POLYMERIZING OLEFIN AND PRODUCTION OF OLEFIN-BASED (CO)POLYMER

Japanese Patent JPH11310609

A

To provide a catalyst for (co)polymerizing olefins, having high polymerization activity and capable of producing a (co)polyolefin having a higher molecular weight and a narrower molecular weight distribution and to provide a method for producing a (co)polyolefin using the same catalyst.

This catalyst for (co)polymerizing olefins is a supported catalyst in which (A) a transition metal compound expressed by formula I {[η-C5R15M1 M12][μ-η-C5R24-SiR32-η-C9R46] [η-C5R55M1X22]} or formula II {[η-C5R65M2 M32][μ-η-C5R74-B-η-C5R84] [η-C5R95M2X42]} [wherein, η-C5R15, η-C5R24, η-C5R55, η-C5R65, η-C5R74, η-C5R84 and η-C5R95 are each a (substituted) indenyl; R3 is a hydrocarbon; B is a crosslinking group containing Si; M1 and M2 are each Ti, Zr or Hf; X1-X4 are each a halogen or the like] and (B) aluminoxane are supported by a fine particle support. A (co)polyolefin is obtained by (co) polymerizing olefins in the presence of this catalyst and an organic aluminum compound.

JP3496955	PRODUCTION OF SOLID CATALYST COMPONENT FOR POLYMERIZING OLEFIN
WO/2018/151790	HAFNOCENE CATALYST COMPOUNDS AND PROCESS FOR USE THEREOF
JP3973765	Olefin polymerization catalyst and polymerization method consisting of transition metal compounds

SHIODA TSUTOMU
SAITO JUN
TSUTSUI MOTOTAKE

JP4273899A

November 09, 1999

February 22, 1999

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CHISSO CORP

C08F4/642; C08F4/6592; C08F210/02; (IPC1-7): C08F4/642; C08F210/02

Tsutomu Toyama (2 outside)

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