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Title:
CATALYZED HYDROCARBYLLITHIUM PROCESS
Document Type and Number:
Japanese Patent JPH05202066
Kind Code:
A
Abstract:

PURPOSE: To provide a producing method of a pure alkyl lithium compd. with high yield.

CONSTITUTION: In the alkylation method of alkali metals with alkylhalides, the alkylation reaction is carried out in a hydrocarbon solvent in the presence of a catalyst expressed by (RR1R2Ma)yA(R3)x. In the formula, R, R1 and R2 are each selected from H, halogen, alkyl, alkenyl, cycloalkyl and aryl; R3 is selected from aryl, 4 to 6-membered heterocyclic carbon-contg. ring, hydroxyalkyl, alkoxyalkyl, monoalkylaminoalkyl and dialkylaminoalkyl; Ma is selected from silicon, carbon, germanium and tin; A is selected from oxygen, sulfur, nitrogen and phosphorus; (x) and (y) are independently 0 to 3.


Inventors:
ROBAATO CHIYAARUZU MORISON
RANDEI UINFURETSUDO HOORU
JIEEMUSU ANSONII SHIYUWAINDOMA
KONRADO UIRIAMU KAMINSUKII
JIYON FURANSHISU ENJIERU
BII TOROI DOOBAA
Application Number:
JP23125192A
Publication Date:
August 10, 1993
Filing Date:
July 16, 1992
Export Citation:
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Assignee:
FMC CORP
International Classes:
B01J31/12; C07B61/00; C07F1/00; C07F1/02; C07F1/04; C07F1/06; C07F7/08; B01J31/02; C07F7/12; (IPC1-7): B01J31/02; B01J31/12; C07B61/00; C07F1/02; C07F1/04; C07F1/06; C07F7/12
Attorney, Agent or Firm:
Takehiko Saito (1 outside)