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Title:
CHEMILUMINESCENT SOLUTION BASED ON SUBSTITUTED ANTHRACENES
Document Type and Number:
Japanese Patent JPH03178942
Kind Code:
A
Abstract:

NEW MATERIAL: A compound of formula I (R is F, Cl, Br, C1-4 alkoxy or phenoxy; R' is C1-4 alkoxy, phenoxy, F or polyalkyleneoxy alkyl ether; n is 1-3, provided that when R is Cl, then R' is not p-methoxy).

EXAMPLE: 9,10-Bis(4-ethoxyphenyl)-2-chloroanthracene.

USE: Chemiluminescent solution.

PROCESS: A compound of formula II obtained by Friedel-Crafts reaction between phthalic anhydride and a 2-phenyl derivative is cyclized in sulfuric acid to give a compound of formula III. After addition of a Grignard reagent (R')nPhMgBr to the product, the reaction mixture is hydrolyzed with ammonium chloride to give a compound of formula IV. The product is reduced with KI, an active acid (e.g. CH3COOH) and sodium phosphite under refluxed conditions to give the compound of formula I.


Inventors:
ANDORE BAN MEERU
JIYATSUKU RADEIJIENSUKII
Application Number:
JP31814590A
Publication Date:
August 02, 1991
Filing Date:
November 26, 1990
Export Citation:
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Assignee:
AMERICAN CYANAMID CO
International Classes:
C09K11/06; B44F1/12; C07C25/22; C07C43/20; C07C43/225; C07C43/29; C07K17/00; C09K11/07; (IPC1-7): C07C25/22; C07C43/225; C07C43/29; C07K17/00; C09K11/06
Domestic Patent References:
JPS62158781A1987-07-14
Attorney, Agent or Firm:
Heiyoshi Odashima