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Title:
COLUMNAR CERIA CATALYST
Document Type and Number:
Japanese Patent JP2012223667
Kind Code:
A
Abstract:

To provide a catalyst consisting of a support containing ceria and an active species supported on the support, which can control the particulate growth of the active species.

The method for producing the catalyst includes: a process for mixing a cerium salt and a strong alkaline aqueous solution to prepare a mixed solution; a process for hydrothermally synthesizing the mixed solution to form the support that contains CeO2 nanorods consisting of a {100} surface and a {110} surface; a process for dispersing the support that contains the CeO2 nanorods in water to prepare a support dispersion liquid; a process for dispersing metal fine particles in water to prepare a metal fine particle-dispersed liquid; and a process for mixing and agitating with heating the support dispersion liquid and the metal particle dispersion liquid to support the metal particles on the support that contains the CeO2 nanorods.


Inventors:
NAGAO SATOSHI
MINAMI MITSURU
Application Number:
JP2011090844A
Publication Date:
November 15, 2012
Filing Date:
April 15, 2011
Export Citation:
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Assignee:
TOYOTA MOTOR CORP
International Classes:
B01D53/86; B01J23/10; B01J32/00; B01J35/02; B01J37/10; C01F17/00
Domestic Patent References:
JP2009208029A2009-09-17
JP2007217265A2007-08-30
JP2005519845A2005-07-07
JP2008150231A2008-07-03
JP2009172593A2009-08-06
Other References:
JPN6014018694; LIU, X. et al: 'Oxygen Vacancy Clusters Promoting Reducibility and Activity of Ceria Nanorods' J. Am. Chem. Soc. Vol.131, No.9, 20090212, p.3140-3141
JPN6014018696; WU, Z. et al: 'Probing Defect Sites on CeO2 Nanocrystals with Well-Defined Surface Planes by Raman Spectroscopy and' Langmuir Vol.26, No.21, 20100709, p.16595-16606
JPN6014018691; MAI, H.-X. et al: 'Shape-Selective Synthesis and Oxygen Storage Behavior of Ceria Nanopolyhedra, Nanorods, and Nanocube' J. Phys. Chem. B Vol.109, No.51, 20051206, p.24380-24385
JPN6014018692; SI, R. et al: 'Shape and Crystal-Plane Effects of Nanoscale Ceria on the Activity of Au-CeO2 Catalysts for the Wate' Angewandte Chemie International Edition Vol.47, No.15, 20080310, p.2884-2887
Attorney, Agent or Firm:
Atsushi Aoki
Takashi Ishida
Tetsuji Koga
Nobuo Sekine
Masaharu Konoue