Title:
錯体
Document Type and Number:
Japanese Patent JP2017526621
Kind Code:
A
Abstract:
本発明は、式（１）のパラジウム（ＩＩ）錯体又は式（２）のパラジウム（ＩＩ）錯体を提供する。Ｒ１、Ｒ２、Ｒ３、Ｒ４、Ｒ５、Ｒ６、Ｒ７、Ｒ８、Ｒ９、Ｒ１０、Ｒ１１、Ｒ１２、Ｒ１８、Ｒ１９、Ｒ２０、Ｒ２１、Ｒ２２、Ｒ２３、Ｒ２４、ｍ、Ｅ、及びＸは、本明細書に記載されている。本発明はまた、錯体の調製方法、並びに炭素−炭素及び炭素−ヘテロ原子カップリング反応におけるその使用を提供する。【選択図】図６
Inventors:
Cola cot, thomas
Chow, Lishan
John Dean Gerris, Andrew
Chow, Lishan
John Dean Gerris, Andrew
Application Number:
JP2016572542A
Publication Date:
September 14, 2017
Filing Date:
March 20, 2015
Export Citation:
Assignee:
JOHNSON MATTHEY PUBLIC LIMITED COMPANY
International Classes:
C07F19/00; C07C17/32; C07C22/08; C07C45/68; C07C49/84
Domestic Patent References:
| JP2017527526A | 2017-09-21 |
Foreign References:
| WO2011161451A1 | 2011-12-29 |
Other References:
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ARNE FICKS, RACHEL M. HINEY, ROSS W. HARRINGTON, DECLAN G. GILHEANY AND LEE J. HIGHAM: "MOP-phosphonites: A novel ligand class for asymmetric catalysis", DALTON TRANSACTIONS, vol. 41, JPN6018041526, 2012, pages 3515 - 3522, ISSN: 0004174224
ARNALD GRABULOSA, GUILLERMO MULLER, JUAN I. ORDINAS, ANTONIO MEZZETTI, MIGUEL ANGEL MAESTRO, MERCE F: "Allylpalladium Complexes with P-Stereogenic Monodentate Phosphines. Application in the Asymmetric Hy", ORGANOMETALLICS, vol. 24, JPN6018041518, 2005, pages 4961 - 4973, XP055008518, ISSN: 0004174216, DOI: 10.1021/om050421v
NINA SVENSEN, PETER FRISTRUP, DAVID TANNER, AND PER-OLA NORRBY: "Memory Effects in Palladium-Catalyzed Allylic Alkykations of 2-Cyclohexen-1-yl Acetate", ADVANCED SYNTHESIS & CATALYSIS, vol. 349, JPN6018041520, 2007, pages 2631 - 2640, XP055189895, ISSN: 0004174217, DOI: 10.1002/adsc.200700315
ARNALD GRABULOSA; GUILLERMO MULLER; ET AL: "BETTER PERFORMANCE OF MONODENTATE P-STEREOGENIC PHOSPHANES COMPARED TO BIDENTATE 以下備考", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. VOL:2010, NR:21, JPN5017004573, 2 June 2010 (2010-06-02), pages 3372 - 3383, ISSN: 0004174218
RODRIGUEZ L I; ROSSELL O; SECO M; ET AL: "PALLADOCARBOSILANE DENDRIMERS AS CATALYSTS FOR THE ASYMMETRIC HYDROVINYLATION OF 以下備考", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. VOL:693, NR:10, JPN5017004574, 15 February 2008 (2008-02-15), CH, pages 1857 - 1860, ISSN: 0004174219
TOSHIMICHI OHMURA; KAZUYUKI OSHIMA; ET AL: "SWITCH OF REGIOSELECTIVITY IN PALLADIUM-CATALYZED SILABORATION OF TERMINAL ALKYNES BY 以下備考", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. VOL:132, NR:35, JPN5017004576, 8 September 2010 (2010-09-08), pages 12194 - 12196, ISSN: 0004174220
PHILIP KISANGA AND ROSS A. WIDENHOEFER: "Development, Synthetic Scope, and Mechanistic Studies of the Palladium-Catalyzed Cycloisomerization", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 122, JPN6018041522, 2000, pages 10017 - 10026, ISSN: 0004174221
P. G. ANIL KUMAR, PASCAL DOTTA, RENE HERMATSCHWEILER, AND PAUL S. PREGOSIN: "Bonding in Palladium(II) and Platinum(II) Allyl MeO- and H-MOP Complexes. Subtle Differences via 13C", ORGANOMETALLICS, vol. 24, JPN6018041532, 2005, pages 1306 - 1314, ISSN: 0004174222
TAMIO HAYASHI, HIROSHI IWAMURA, MASAKI NAITO, YONETATSU MATSUMOTO, AND YASUHIRO UOZUMI: "Catalytic Asymmetric Reduction of Allylic Esters with Formic Acid Catalyzed by Palladium-MOP Complex", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 116, JPN6018041525, 1994, pages 775 - 776, XP002031407, ISSN: 0004174223, DOI: 10.1021/ja00081a051
J. W. FALLER AND NIKOS SARANTOPOULOS: "Retention of Configuration and Regiochemistry in Allylic Alkylations via the Memory Effect", ORGANOMETALLICS, vol. 23, JPN6018041529, 2004, pages 2179 - 2185, XP055190728, ISSN: 0004174225, DOI: 10.1021/om0306224
ARNE FICKS, RACHEL M. HINEY, ROSS W. HARRINGTON, DECLAN G. GILHEANY AND LEE J. HIGHAM: "MOP-phosphonites: A novel ligand class for asymmetric catalysis", DALTON TRANSACTIONS, vol. 41, JPN6018041526, 2012, pages 3515 - 3522, ISSN: 0004174224
ARNALD GRABULOSA, GUILLERMO MULLER, JUAN I. ORDINAS, ANTONIO MEZZETTI, MIGUEL ANGEL MAESTRO, MERCE F: "Allylpalladium Complexes with P-Stereogenic Monodentate Phosphines. Application in the Asymmetric Hy", ORGANOMETALLICS, vol. 24, JPN6018041518, 2005, pages 4961 - 4973, XP055008518, ISSN: 0004174216, DOI: 10.1021/om050421v
NINA SVENSEN, PETER FRISTRUP, DAVID TANNER, AND PER-OLA NORRBY: "Memory Effects in Palladium-Catalyzed Allylic Alkykations of 2-Cyclohexen-1-yl Acetate", ADVANCED SYNTHESIS & CATALYSIS, vol. 349, JPN6018041520, 2007, pages 2631 - 2640, XP055189895, ISSN: 0004174217, DOI: 10.1002/adsc.200700315
ARNALD GRABULOSA; GUILLERMO MULLER; ET AL: "BETTER PERFORMANCE OF MONODENTATE P-STEREOGENIC PHOSPHANES COMPARED TO BIDENTATE 以下備考", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. VOL:2010, NR:21, JPN5017004573, 2 June 2010 (2010-06-02), pages 3372 - 3383, ISSN: 0004174218
RODRIGUEZ L I; ROSSELL O; SECO M; ET AL: "PALLADOCARBOSILANE DENDRIMERS AS CATALYSTS FOR THE ASYMMETRIC HYDROVINYLATION OF 以下備考", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. VOL:693, NR:10, JPN5017004574, 15 February 2008 (2008-02-15), CH, pages 1857 - 1860, ISSN: 0004174219
TOSHIMICHI OHMURA; KAZUYUKI OSHIMA; ET AL: "SWITCH OF REGIOSELECTIVITY IN PALLADIUM-CATALYZED SILABORATION OF TERMINAL ALKYNES BY 以下備考", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. VOL:132, NR:35, JPN5017004576, 8 September 2010 (2010-09-08), pages 12194 - 12196, ISSN: 0004174220
PHILIP KISANGA AND ROSS A. WIDENHOEFER: "Development, Synthetic Scope, and Mechanistic Studies of the Palladium-Catalyzed Cycloisomerization", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 122, JPN6018041522, 2000, pages 10017 - 10026, ISSN: 0004174221
P. G. ANIL KUMAR, PASCAL DOTTA, RENE HERMATSCHWEILER, AND PAUL S. PREGOSIN: "Bonding in Palladium(II) and Platinum(II) Allyl MeO- and H-MOP Complexes. Subtle Differences via 13C", ORGANOMETALLICS, vol. 24, JPN6018041532, 2005, pages 1306 - 1314, ISSN: 0004174222
TAMIO HAYASHI, HIROSHI IWAMURA, MASAKI NAITO, YONETATSU MATSUMOTO, AND YASUHIRO UOZUMI: "Catalytic Asymmetric Reduction of Allylic Esters with Formic Acid Catalyzed by Palladium-MOP Complex", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 116, JPN6018041525, 1994, pages 775 - 776, XP002031407, ISSN: 0004174223, DOI: 10.1021/ja00081a051
J. W. FALLER AND NIKOS SARANTOPOULOS: "Retention of Configuration and Regiochemistry in Allylic Alkylations via the Memory Effect", ORGANOMETALLICS, vol. 23, JPN6018041529, 2004, pages 2179 - 2185, XP055190728, ISSN: 0004174225, DOI: 10.1021/om0306224
Attorney, Agent or Firm:
Sonoda/Kobayashi Patent Business Corporation