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Title:
COMPOSITION FOR OXIDE SUPERCONDUCTOR, PRODUCTION OF RAW MATERIAL FOR OXIDE SUPERCONDUCTOR USING SAME COMPOSITION AND PRODUCTION OF OXIDE SUPERCONDUCTOR USING SAME COMPOSITION
Document Type and Number:
Japanese Patent JPH0492820
Kind Code:
A
Abstract:

PURPOSE: To obtain the subject raw material for an oxide superconductor capable of producing an oxide superconductor having a high critical temperature and an improved critical current density by calcining and crushing a mixture raw material containing Bi, Pb, Sr, Ba, Ca and Cu in a specified atomic ratio.

CONSTITUTION: Raw materials such as bismuth trioxide, lead monoxide, strontium carbonate, barium carbonate, calcium carbonate and cupric oxide are weighed and mixed so that the atomic ratio of (Bi:Pb:Sr:Ba:Ca:Cu) may be (1.3-2.2):(0.2-0.8):(1.4-2.2):(A):(1.6-2.4):(2.8-3.2) (provided that A≤0.6; 2≤Bi/Pb≤9.6; 1.7≤Bi+Pb≤2.6, Sr+Ba≤2.2). The resultant mixture raw material is then calcined and crushed to obtain the raw material for an oxide superconductor. By burning the obtained raw material for an oxide superconductor, an oxide superconductor containing a large amount of a high temperature phase showing a critical temperature in the vicinity of 110K can be obtained.


Inventors:
SHIMODA SHUICHIRO
KUWAJIMA HIDEJI
ISHIHARA MINORU
SUMIYA KEIJI
ASHIZAWA TORANOSUKE
Application Number:
JP20542890A
Publication Date:
March 25, 1992
Filing Date:
August 02, 1990
Export Citation:
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Assignee:
HITACHI CHEMICAL CO LTD
International Classes:
C04B35/00; C01G1/00; C01G29/00; C04B35/45; H01B12/00; H01B13/00; H01L39/24; (IPC1-7): C01G29/00; C04B35/00; H01B12/00; H01B13/00; H01L39/24
Attorney, Agent or Firm:
Kunihiko Wakabayashi