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Title:
CYCLIC PHENOL SULFIDE METAL COMPLEX, CATALYST THEREFROM, AND ANALYSIS OF HYDROGEN PEROXIDE
Document Type and Number:
Japanese Patent JP2000191658
Kind Code:
A
Abstract:

To obtain a cyclic phenol sulfide metal complex usable in applications as a catalyst for various chemical reactions or information/electronic material, in particular having peroxidase-like activity and high activity to hydrolyze phosphoric diesters, and easily hybridizable with a base sequence recognition site as well.

This metal complex is obtained by bringing at least one kind of metal selected from among group VIII, groups IA to VIIA, groups IB and IIIB metals into contact with a cyclic phenol sulfide pref. of the formula (X1 is H, a hydrocarbon, acyl, or the like; Y1 is H, a hydrocarbon, halohydrocarbon, halogen, or the like, Z1 is Sm1 SO or SO2; m1 is an integer of 1-7; n1 is an integer of 4-8). This metal complex is used as a catalyst for oxidation reaction using hydrogen peroxide or a catalyst for hydrolysis reaction of a phosphoric diester. Hydrogen peroxide can be analyzed using the above catalyst for hydrolysis reaction.


Inventors:
Odo, Junichi
Kawahara, Nobuko
Akashi, Koichi
Miyano, Sotaro
Iki, Nobuhiko
Morohashi, Naoya
Takeya, Haruhiko
Miyanari, Setsuko
Kumagai, Hitoshi
Application Number:
JP1999000144750
Publication Date:
July 11, 2000
Filing Date:
May 25, 1999
Export Citation:
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Assignee:
COSMO RESEARCH INST
COSMO OIL CO LTD
International Classes:
B01J31/22; C07C29/12; C07C201/12; C07C205/22; C07D341/00; C07F3/00; C07F3/02; C07F5/00; C07F15/02; C07F15/06; C09B55/00; G01N21/77; G01N31/00; G01N31/10; (IPC1-7): C07D341/00; B01J31/22; C07F5/00; C09B55/00; G01N21/77; G01N31/00
Attorney, Agent or Firm:
折口 信五