NEW MATERIAL:The compound of formula I (R1 is cyclic group, i.e. carbon ring group or heterocyclic group; Z is alkylene, alkenylene, oxyalkylene, etc.; A is halogen, alkyl, alkenyl, etc.; B is O, carbonyl, thio, sulfonyl, etc.; R2 is H or methyl; l is 0W5; when l is ≥2, plural A may be different; m is 4W20; α and β are 0W4; α+β is ≥1; p is 1 or 2; q is 0 or 1; q=0 when p=1, and q is 0 or 1 when p=2; in the latter case, the R1, A, l, α, and β at the right and left hands may be different).
EXAMPLE: N-(4-Phenoxybutyl)acrylamide.
USE: Useful as an adhesive, coating, etc.
PREPARATION: The compound of formula I can be prepared by reacting the cyclic halogen-substituted ether compound of formula II (A' is alkyl, etc.; X is halogen) with the unsaturated amide compound of formula III in an aprotic polar solvent in the presence of a strong basic substance.
NITSUTA ATSUHIKO
TANAKA TOMIO
KAMIO HIDEO
