To obtain a new diacetylene compound having a large anisotropy of refractive index and useful as a constituting material for liquid crystal elements or as a constituent for liquid crystal compositions.
A compound of formula I [A, B are each independently 1,4- phenylene, 1,4-(2-fluoro)phenylene, etc.; (l), (m) are each independently 0, 1; E, G are each independently F, methyl, methoxy, R1, R2 are each independently H, F, CF3, etc.; when A, B are simultaneously not 1,4-phenylene, etc., at the one of R1, R2 is a not a linear alkyl, etc.]. The compound of formula I is obtained by reacting a compound of formula II with a compound of formula III in the presence of a basic catalyst such as a copper chloride catalyst, a hydroxy amine hydrochloride or ethylamine.
FUJISAWA KOICHI
FUJIMOTO YUKARI
MINAMII MASAYOSHI
JPH06211704A | 1994-08-02 | |||
JPH0849172A | 1996-02-20 | |||
JPS56123903A | 1981-09-29 | |||
JPH0929882A | 1997-02-04 | |||
JPH0940958A | 1997-02-10 | |||
JPH08133996A | 1996-05-28 | |||
JPS60217213A | 1985-10-30 |
US5457235A | 1995-10-10 | |||
WO1995012378A2 | 1995-05-11 | |||
DE4013297A1 | 1991-10-31 |
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