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Title:
ETHYLENE POLYMER AND THERMOPLASTIC RESIN COMPOSITION CONTAINING THE SAME
Document Type and Number:
Japanese Patent JPH0782322
Kind Code:
A
Abstract:

PURPOSE: To obtain an ethylene polymer which can have a regulated melt rheology activation energy and have regulated physical properties including density, melting point, and crystallinily without incorporation of any ingredient, and which has excellent processability, a high melting point, and excellent impact resistance by polymerizing ethylene using a specific polymerization catalyst under a specific polymerization condition.

CONSTITUTION: Ethylene is polymerized using a polymerization catalyst comprising a suitable combination of a transition metal compound (A) and a compound capable of forming an ionic complex with either the compound (A) or a derivative thereof. The polymer obtained has terminal unsaturated groups and contains no quaternary carbon in the main chain. The polymer has a density of 0.85-0.95g/cm3, a weight-average mol.wt. in terms of polyethylene of 5,000-2,000,000, the ratio of weight-average mol.wt. to number-average mol.wt. (Mw/Mn) in terms of polyethylene of 1.5-70, a melt rheology activation energy of 8-20kcal/mol, and a β dispersion peak at 0 to -100°C in its loss modulus curve.


Inventors:
SHIGUMA HARUO
MACHIDA SHUJI
Application Number:
JP22920093A
Publication Date:
March 28, 1995
Filing Date:
September 14, 1993
Export Citation:
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Assignee:
IDEMITSU KOSAN CO
International Classes:
C08F4/653; C08F4/60; C08F4/6592; C08F8/00; C08F110/02; C08L23/06; C08L101/00; (IPC1-7): C08F110/02; C08F4/653; C08L23/06
Attorney, Agent or Firm:
Otani Ho



 
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