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Title:
ETHYLENE POLYMERIZATION CATALYST
Document Type and Number:
Japanese Patent JPH02235910
Kind Code:
A
Abstract:

PURPOSE: To obtain an ethylene polymerization catalyst which has activity at least equivalent to that attained when an accelerator is used by mixing a reaction product of a V compound with a specified electron donor with an alkylhalosilane, a silica support and a specified Al promoter.

CONSTITUTION: This catalyst is obtained by mixing a V compound (e.g. vanadium trihalide) and an electron donor in the form of a liquid or an organic Lewis acid in which the V compound is soluble (e.g. alkyl aliphatic or aromatic carboxylate) (A) with an alkylhalosilane (B) represented by the formula (wherein R is a 1-10C alkyl; X is a halogen; (a) is 1 or 2; (b) is 2 or 3; and a+b=4 (e.g. methyltrichlorosilane), a silica support (C) impregnated with components A and B and a hydrocarbylaluminum promoter (D). This has activity at least equivalent to that attained when an accelerator is used.


Inventors:
SARI BESU SAMIYUERUZU
FUREDERITSUKU JIYON KARORU
Application Number:
JP2977290A
Publication Date:
September 18, 1990
Filing Date:
February 13, 1990
Export Citation:
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Assignee:
UNION CARBIDE CHEM PLASTIC
International Classes:
C08F4/60; C08F4/68; C08F10/00; C08F10/02; (IPC1-7): C08F4/68; C08F10/02
Domestic Patent References:
JPS61151206A1986-07-09
Attorney, Agent or Firm:
Motohiro Kurauchi (1 outside)