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Title:
EXPANDABLE THERMOPLASTIC RESIN PARTICLE AND ITS PREPARATION
Document Type and Number:
Japanese Patent JPS59204629
Kind Code:
A
Abstract:

PURPOSE: To obtain the titled resin particles having heat resistance and solvent resistance, by subjecting a specific amount of α-methylstyrene, a specified amount of acrylonitrile and a specific monomer to suspension polymerization with a bifunctional organic peroxide as an initiator and an easily volatile blowing agent at a specific temperature.

CONSTITUTION: 10W80wt% α-methylstyrene, 5W50wt% acrylonitrile, 0W70wt% one or more monomers of styrene, methyl methacrylate, vinyltoluene, and t- butylstyrene and a bifunctional organic peroxide (preferably producing t-butoxy radical) as an initiator are subjected to suspension polymerization at 80W130°C by adding 2W15wt% easily volatile blowing agent during polymerization or after polymerization. When high expansion is required, preferably 0.5W2.0wt% solvent or plasticizer is added to the reaction system.


Inventors:
MORI KIYOSHI
NAKAGAWA MASAO
Application Number:
JP7964583A
Publication Date:
November 20, 1984
Filing Date:
May 06, 1983
Export Citation:
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Assignee:
KANEGAFUCHI CHEMICAL IND
International Classes:
C08F4/28; C08F4/32; C08J9/16; C08F212/10; C08F212/12; C08F220/42; C08F220/44; C08J9/18; (IPC1-7): C08J9/16
Domestic Patent References:
JPS5765735A1982-04-21
JPS5319397A1978-02-22
Attorney, Agent or Firm:
Shinichi Asano