Title:
FERROCENE-BASED COMPOUND AND PALLADIUM CATALYST BASED THEREON FOR THE ALKOXYCARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUND
Document Type and Number:
Japanese Patent JP2017061443
Kind Code:
A
Abstract:
PROBLEM TO BE SOLVED: To provide a novel ferrocene-based compound as a catalyst ligand to achieve improved conversion in the alkoxycarbonylation reaction of long-chain olefins such as 2-octene or di-n-butene.SOLUTION: A Pd complex comprising a compound of formula (I) is used for the alkoxycarbonylation: where R-Rare each independently selected from -(C-C)- alkyl, -(C-C)- cycloalkyl, -(C-C)- heterocycloalkyl, -(C-C)- aryl, and -(C-C)- heteroaryl; and at least one of the R-Rradicals is a -(C-C)- heteroaryl radical having at least six membered ring atoms.SELECTED DRAWING: Figure 1
Inventors:
DONG KAI-WU
NEUMANN HELFRIED
RALF JACKSTELL
BELLER MATTHIAS
ROBERT FRANKE
DIETER HESS
KATRIN MARIE DYBALLA
DIRK FRIDAG
FRANK GEILEN
NEUMANN HELFRIED
RALF JACKSTELL
BELLER MATTHIAS
ROBERT FRANKE
DIETER HESS
KATRIN MARIE DYBALLA
DIRK FRIDAG
FRANK GEILEN
Application Number:
JP2016141022A
Publication Date:
March 30, 2017
Filing Date:
July 19, 2016
Export Citation:
Assignee:
EVONIK DEGUSSA GMBH
International Classes:
C07F19/00; B01J31/28; C07C67/38; C07C69/24; C07C69/34; C07C69/533; C07C69/608; C07C69/74; C07C69/75; C07F9/58; C07F15/00
Domestic Patent References:
| JPH09501691A | 1997-02-18 | |||
| JPS6490222A | 1989-04-06 | |||
| JP2013516449A | 2013-05-13 | |||
| JPH04215851A | 1992-08-06 |
Foreign References:
| WO2012111737A1 | 2012-08-23 | |||
| US5679831A | 1997-10-21 |
Other References:
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, vol. 2012(21), JPN6020000665, 2012, pages 4018 - 4033, ISSN: 0004191808
Attorney, Agent or Firm:
Kenji Akatsuka
Yasuyuki Sakata
Ken Shibuya
Yasuyuki Sakata
Ken Shibuya