To obtain fine Si particles having a large surface area and an open three-dimensional network structure by evaporating metallic Si in the lower part of a chamber by irradiation with pulsated laser in the presence of oxygen- free inert carrier gas and carrying out cooling.
A vacuum chamber is composed of two horizontal circular stainless steel places separated with a circular glass ring, a metallic Si rod is fitted near the lower plate and oxygen-free insert carrier gas is introduced into the chamber. The Si rod is evaporated by irradiation with pulsated laser from Y-Al-garnet-Nd laser through a mirror to generate metallic Si vapor and metallic Si atoms in the vapor are clustered in the chamber. The resultant cluster is condensed on a cooling plate cooled to ≤120°K to obtain a porous material consisting of fine Si particles of 5-50nm diameter and emitting luminescence of 600-640nm max. wavelength after irradiation with UV.
DANIERU GUREIBAA
UDO SHII PEANISU
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