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Title:
FIXED REAGENT FOR OXIDATION REACTION
Document Type and Number:
Japanese Patent JP3958101
Kind Code:
B2
Abstract:

PROBLEM TO BE SOLVED: To improve Corey-Kim oxidation of an alcohol.
SOLUTION: The reagent for oxidation reaction of an alcohol comprises a compound represented by the formula: P-X1-SR (I) (wherein P is a polymer residue; X1 is a spacer; R is H or CH3). The reagent reduces progress of adverse reaction and enables selective production of a carbonyl compound.


Inventors:
Yukinori Sumino
Application Number:
JP2002105329A
Publication Date:
August 15, 2007
Filing Date:
April 08, 2002
Export Citation:
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Assignee:
Shionogi Pharmaceutical Co., Ltd.
International Classes:
B01J31/06; C07D519/06; B01J31/02; C07C45/29; C07C47/02; C07C47/232; C07C47/54; C07C269/06; C07C271/18; C07C323/59; C07J63/00; C08F8/00; C08F8/34; C08F12/08; (IPC1-7): C08F8/00; B01J31/02; C07C45/29; C07C47/02; C07C47/232; C07C47/54; C07C269/06; C07C271/18; C08F12/08; //C07C323/59; C07D519/06; C07J63/00
Domestic Patent References:
JP2000501721A
JP7289912A
JP2001137710A
Other References:
Guy A. Crosby, Ned M. Weinshenker, and Hong-Sun Uh,'Polymeric Reagents. III. Synthesis of an Insoluble Polymeric Thioanisole and Its Utilization for the Oxidation of Alcohols',Journal of the American Chemical Society,1975年,Vol.97 No.8,pp.2232-2235
Attorney, Agent or Firm:
Hideaki Yamauchi
Kenichi Sugita