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Title:
FLAME-RETARDANT POLYETHER-ESTER ELASTIC FIBER
Document Type and Number:
Japanese Patent JPH06173115
Kind Code:
A
Abstract:

PURPOSE: To obtain the subject fiber having high flame retardancy and elastic recovery comprising an elastomer having the hard segment of a copolymer of polalkylene terephthalate and a phosphorus-containing compound and the soft segment of polytetramethylene glycol.

CONSTITUTION: In the reactor, dimethyl terephthalate(DMT), an organophosphorus compound having ester-forming groups of formula I (R1, R2 are alkyl, aryl or alkoxy; X is trivalent aliphatic group) or formula II (Ar is trivalent aromatic group; E is alkylene; (m), (n) are integers the total of which is 2 to 20) and 1,4-butanediol or the like are mixed at a molar ratio of DMT/the phosphorus compound at 80/20 to effect the ester-interchange reaction in the presence of a catalyst, under a normal pressure at 210°C to form the hard segment. Then, polytetramethylene glycol of 500 to 5,000 average molecular weight is added as a soft segment and polycondensation reaction is performed at 250°C under the pressure of less than 1 Torr to give the objective flame-retardant elastic fibers.


Inventors:
OSAWA TSUNEYUKI
UEDA ATSUKO
Application Number:
JP35028392A
Publication Date:
June 21, 1994
Filing Date:
December 03, 1992
Export Citation:
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Assignee:
NIPPON ESTER CO LTD
International Classes:
C08G63/672; C08G63/66; C08G63/692; D01F6/84; D01F6/86; (IPC1-7): D01F6/86; C08G63/672; C08G63/692; D01F6/84; D01F6/86
Attorney, Agent or Firm:
Kodama Yuzo



 
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