Title:
FLUORINE-CONTAINING BISAMIC ACID COMPOUND, ITS PRODUCTION AND PRODUCTION OF FLUORINE-CONTAINING THERMOSETTING BISIMIDE COMPOUND
Document Type and Number:
Japanese Patent JP3042137
Kind Code:
B
Abstract:
PURPOSE: To obtain the subject compound having high fluorine content and easily giving a thermosetting bisimide useful as a raw material for polyimide, polyamide, etc., by reacting a specific fluorine-containing aromatic diamine compound with an ethylenically unsaturated dicarboxylic acid anhydride.
CONSTITUTION: The objective fluorine-containing bisamic acid expressed by formula III and easily giving a thermosetting bisimide compound useful as a raw material for polyimide, polyamide, etc., can be produced by reacting a fluorine-containing aromatic diamine compound of formula I [Rf is group of the formula CnF2n-1((n) is integer of 6-12) which contains a double bond and may be properly branched; two amino groups are bonded to o-, m- or p-site relative to the ester group] [e.g. 5-(perfluorononenyloxy)isophthalic acid bis(4-aminophenyl ester) l with an ethylenically unsaturated dicarboxylic acid anhydride expressed by formula II (D is dicarboxylic acid residue having ethylenically unsaturated double bond) (e.g. maleic anhydride).
Inventors:
Takeda, Shinji
Hasegawa, Yuji
Yusa, Masami
Miyadera, Yasuo
Hasegawa, Yuji
Yusa, Masami
Miyadera, Yasuo
Application Number:
JP1992000037346
Publication Date:
March 10, 2000
Filing Date:
February 25, 1992
Export Citation:
Assignee:
HITACHI CHEM CO LTD
International Classes:
B21B35/04; B21B35/14; B22D11/06; B21B13/02; B21B27/10; B21B31/02; B21B31/06; B21B35/00; B21B35/12; (IPC1-7): C07C233/27; C07D207/452; C08F222/40
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