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Title:
炭素-ヘテロ原子間及び炭素-炭素間結合の銅を触媒とした形成
Document Type and Number:
Japanese Patent JP2004536798
Kind Code:
A
Abstract:
The present invention provides a method represented by Scheme 1: wherein X represents I, Br, Cl, alkylsulfonate, or arylsulfonate; Z represents optionally substituted aryl, heteroaryl or alkenyl; L represents hydrogen or a negative charge; catalyst comprises a copper atom or ion, and a ligand; base represents a Bronsted base; R represents H, optionally substituted alkyl, cycloalkyl, aralkyl, aryl, or heteroaryl; R' represents independently for each occurrence H, alkyl, cycloalkyl, aralkyl, aryl, or heteroaryl, formyl, acyl, -CO 2 R", -C(O)N(R) 2 , sulfonyl, -P(O)(OR") 2 , -CN, or -NO 2 ; R" represents independently for each occurrence optionally substituted alkyl, cycloalkyl, aralkyl, aryl, or heteroaryl; and C (R') 2 (R) taken together may represent nitrile.

Inventors:
Buckwold, Stephen, Elle.
Cala Perth, Artis
Antilla, John, C.
Job, Gabriel, E.
Walter, Martina
Kwon, Hook, Wai.
Norman, Gero
Hennessy, Edward, Jay.
Application Number:
JP2002583366A
Publication Date:
December 09, 2004
Filing Date:
April 24, 2002
Export Citation:
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Assignee:
MASSACHUSETTS INSTITUTE OF TECHNOLOGY
International Classes:
B01J31/26; C07B37/04; C07B41/04; C07B43/04; C07B61/00; C07C41/16; C07C41/24; C07C43/15; C07C43/20; C07C43/23; C07C45/68; C07C45/71; C07C49/84; C07C51/353; C07C59/64; C07C67/343; C07C69/612; C07C209/10; C07C211/48; C07C211/53; C07C211/54; C07C213/02; C07C213/08; C07C215/16; C07C215/70; C07C217/48; C07C217/82; C07C221/00; C07C227/08; C07C227/18; C07C229/56; C07C231/08; C07C231/12; C07C233/07; C07C233/25; C07C233/40; C07C233/51; C07C233/58; C07C233/65; C07C233/66; C07C233/75; C07C233/80; C07C233/81; C07C237/40; C07C241/04; C07C243/38; C07C249/02; C07C249/16; C07C251/18; C07C251/86; C07C253/14; C07C253/30; C07C255/23; C07C269/06; C07C271/28; C07C273/18; C07C275/32; C07C277/08; C07C279/18; C07C281/02; C07C303/38; C07C311/21; C07C319/20; C07D205/08; C07D207/16; C07D207/267; C07D207/27; C07D207/323; C07D209/08; C07D209/14; C07D209/16; C07D209/48; C07D209/86; C07D211/26; C07D211/76; C07D213/30; C07D213/64; C07D213/65; C07D213/74; C07D215/38; C07D221/12; C07D231/12; C07D231/56; C07D233/32; C07D233/34; C07D233/58; C07D235/06; C07D235/08; C07D237/32; C07D239/42; C07D245/06; C07D249/08; C07D249/18; C07D263/22; C07D273/08; C07D295/02; C07D295/023; C07D295/033; C07D295/073; C07D307/79; C07D333/36; C07D333/66; C07D401/04; C07D405/12; C07D407/12; C07D409/04; C07D471/04; C07D473/00; C07D521/00; C07F9/38; C07F9/40; C07C323/41; C07D207/26; C07D207/32; (IPC1-7): C07C233/81; B01J31/26; C07C41/24; C07C43/15; C07C43/20; C07C43/23; C07C45/68; C07C49/84; C07C51/353; C07C59/64; C07C67/343; C07C69/612; C07C209/10; C07C211/48; C07C211/53; C07C211/54; C07C213/02; C07C215/16; C07C215/70; C07C217/48; C07C217/82; C07C227/08; C07C229/56; C07C231/08; C07C233/07; C07C233/25; C07C233/40; C07C233/51; C07C233/58; C07C233/65; C07C233/66; C07C233/75; C07C233/80; C07C237/40; C07C241/04; C07C243/38; C07C249/02; C07C249/16; C07C251/18; C07C251/86; C07C253/30; C07C255/23; C07C271/28; C07C273/18; C07C275/32; C07C277/08; C07C279/18; C07C281/02; C07C311/21; C07D205/08; C07D207/323; C07D209/08; C07D209/48; C07D209/86; C07D211/76; C07D213/30; C07D213/65; C07D231/12; C07D231/56; C07D233/34; C07D233/58; C07D235/08; C07D237/32; C07D239/42; C07D245/06; C07D263/22; C07D295/02; C07D307/79; C07D333/36; C07D401/04; C07D409/04; C07D471/04; C07D473/00; C07F9/38
Domestic Patent References:
JPH03148235A1991-06-25
JP2000256276A2000-09-19
JPH11130738A1999-05-18
JPH09323958A1997-12-16
JPH09323959A1997-12-16
JPH10212267A1998-08-11
JPH10212268A1998-08-11
JPH10212269A1998-08-11
JPH03215448A1991-09-20
JPH10139742A1998-05-26
JPH11199550A1999-07-27
JPS6335548A1988-02-16
Attorney, Agent or Firm:
Junji Endo
Tomimasa Konishi
Tomoko Nakamura