Title:
炭素-ヘテロ原子間及び炭素-炭素間結合の銅を触媒とした形成
Document Type and Number:
Japanese Patent JP5291854
Kind Code:
B2
Abstract:
The present invention provides a method represented by Scheme 1:
wherein
X represents I, Br, Cl, alkylsulfonate, or arylsulfonate;
Z represents optionally substituted aryl, heteroaryl or alkenyl;
L represents hydrogen or a negative charge;
catalyst comprises a copper atom or ion, and a ligand;
base represents a Bronsted base;
R represents H, optionally substituted alkyl, cycloalkyl, aralkyl, aryl, or heteroaryl;
R' represents independently for each occurrence H, alkyl, cycloalkyl, aralkyl, aryl, or heteroaryl, formyl, acyl, -CO 2 R", -C(O)N(R) 2 , sulfonyl, -P(O)(OR") 2 , -CN, or -NO 2 ;
R" represents independently for each occurrence optionally substituted alkyl, cycloalkyl, aralkyl, aryl, or heteroaryl; and
C (R') 2 (R) taken together may represent nitrile.
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Inventors:
Buckwold, Stephen, Elle.
Cala Perth, Artis
Antilla, John, C.
Job, Gabriel, E.
Woolenbrocc, Martina
Kwon, Hook, Wai.
Norman, Gero
Hennessy, Edward, Jay.
Cala Perth, Artis
Antilla, John, C.
Job, Gabriel, E.
Woolenbrocc, Martina
Kwon, Hook, Wai.
Norman, Gero
Hennessy, Edward, Jay.
Application Number:
JP2002583366A
Publication Date:
September 18, 2013
Filing Date:
April 24, 2002
Export Citation:
Assignee:
MASSACHUSETTS INSTITUTE OF TECHNOLOGY
International Classes:
C07C233/81; B01J31/26; C07B37/04; C07B41/04; C07B43/04; C07B61/00; C07C41/16; C07C41/24; C07C43/15; C07C43/20; C07C43/23; C07C45/68; C07C45/71; C07C49/84; C07C51/353; C07C59/64; C07C67/343; C07C69/612; C07C209/10; C07C211/48; C07C211/53; C07C211/54; C07C213/02; C07C213/08; C07C215/16; C07C215/70; C07C217/48; C07C217/82; C07C221/00; C07C227/08; C07C227/18; C07C229/56; C07C231/08; C07C231/12; C07C233/07; C07C233/25; C07C233/40; C07C233/51; C07C233/58; C07C233/65; C07C233/66; C07C233/75; C07C233/80; C07C237/40; C07C241/04; C07C243/38; C07C249/02; C07C249/16; C07C251/18; C07C251/86; C07C253/14; C07C253/30; C07C255/23; C07C269/06; C07C271/28; C07C273/18; C07C275/32; C07C277/08; C07C279/18; C07C281/02; C07C303/38; C07C311/21; C07C319/20; C07D205/08; C07D207/16; C07D207/267; C07D207/27; C07D207/323; C07D209/08; C07D209/14; C07D209/16; C07D209/48; C07D209/86; C07D211/26; C07D211/76; C07D213/30; C07D213/64; C07D213/65; C07D213/74; C07D215/38; C07D221/12; C07D231/12; C07D231/56; C07D233/32; C07D233/34; C07D233/58; C07D235/06; C07D235/08; C07D237/32; C07D239/42; C07D245/06; C07D249/08; C07D249/18; C07D263/22; C07D273/08; C07D295/02; C07D295/023; C07D295/033; C07D295/073; C07D307/79; C07D333/36; C07D333/66; C07D401/04; C07D405/12; C07D407/12; C07D409/04; C07D471/04; C07D473/00; C07D521/00; C07F9/38; C07F9/40; C07C323/41; C07D207/26; C07D207/32
Domestic Patent References:
JP2000256276A | ||||
JP11130738A | ||||
JP9323958A | ||||
JP9323959A | ||||
JP10212267A | ||||
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Foreign References:
US2490813 |
Other References:
Fuk Yee Kwong et al.,Organic Letters, Vol.4, No.4, 2002, p.581-584
Attorney, Agent or Firm:
Mizuno Yuuki
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