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Title:
GLASS FIBER SIZING COMPOSITION AND METHOD OF USING THE SAME
Document Type and Number:
Japanese Patent JPH0881882
Kind Code:
A
Abstract:

To obtain the subject sizing composition containing a polymer of specific monomers, capable of improving wettability of reinforcing glass fibers for FRP and clarity of FRP.

This sizing composition comprises a low-molecular weight polymer (effective for clarity) is obtained by subjecting (a) (meth)acrylic acid, (b) a 1-8C alkyl ester, glycidyl ester or a 1-4C hydroxyalkyl ester of acrylic acid or methacrylic acid, (c) a vinyl ester of a ≤10C saturated aliphatic monocarboxylic acid (e.g. vinyl acetate, etc.), (d) (meth)acrylamide, its N- substituted derivative or vinyl ether, (e) an allyl (or methallyl) saturated aliphatic monocarboxylate, (f) itaconic acid and/or maleic acid and/or fumaric acid diester and (g) a monomer such as styrene, etc., as monomers to emulsion polymerization and has <0.4 dl/g intrinsic viscosity. The polymer is formulated with a silane coupling agent, a lubricant, acetic acid, etc., to give the objective sizing composition. A reinforcing glass fiber is treated with the sizing composition to effectively improve wettability of the glass fiber.


Inventors:
CHIYAARUZU AARU KII
IENNJIYAA SHIN
Application Number:
JP18720495A
Publication Date:
March 26, 1996
Filing Date:
July 24, 1995
Export Citation:
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Assignee:
NAT STARCH CHEM INVEST
International Classes:
C03C25/28; C03C25/285; C08F212/08; C08J5/08; C08F218/08; C08F220/18; C08K9/08; D06M13/02; D06M13/188; D06M13/503; D06M13/507; D06M15/263; D06M15/333; D06M101/00; (IPC1-7): D06M15/263; C08J5/08; D06M15/333
Domestic Patent References:
JPH06106633A1994-04-19
JPH06108355A1994-04-19
JPH01166946A1989-06-30
Attorney, Agent or Firm:
石田 敬 (外3名)